Visible light assisted photocatalytic activity of TiO2-metal vanadate (M=Sr, Ag and Cd) nanocomposites

K. Vignesh, R. Hariharan, M. Rajarajan, A. Suganthi

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

TiO2-metal vanadate nanocomposites (TiO2-MV) were synthesized by the precipitation method and successfully characterized using UV-visible diffuse reflectance spectroscopy (UV-vis-DRS), powder X-ray diffraction (XRD), photoluminescence (PL) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX) techniques. The photocatalytic activity of TiO 2-MV was investigated for the degradation of fast green (FG) dye under visible light irradiation. The photocatalytic activity of TiO 2-silver vanadate [TiO2-Ag3VO4] was found to be much higher than that of TiO2-cadmium vanadate [TiO 2-CdV2O6], TiO2-strontium vanadate [TiO2-Sr3(VO4)2] and TiO 2. The effect of operational parameters such as pH, photocatalyst concentration and initial dye concentration on the photodegradation of FG was examined in detail. The mineralization of FG was confirmed by chemical oxygen demand (COD) and total organic carbon (TOC) measurements. Moreover, TiO 2-Ag3VO4 was found to be a reusable photocatalyst.

Original languageEnglish
Pages (from-to)1521-1530
Number of pages10
JournalMaterials Science in Semiconductor Processing
Volume16
Issue number6
DOIs
Publication statusPublished - 2013
Externally publishedYes

Fingerprint

Vanadates
vanadates
Photocatalysts
Nanocomposites
nanocomposites
Dyes
Metals
Photoluminescence spectroscopy
Chemical oxygen demand
Photodegradation
Strontium
Organic carbon
Cadmium
metals
X ray powder diffraction
Silver
Coloring Agents
dyes
Irradiation
Spectroscopy

Keywords

  • Metal vanadate
  • Nanocomposite
  • Photocatalysis
  • TiO
  • Visible light

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering
  • Mechanics of Materials

Cite this

Visible light assisted photocatalytic activity of TiO2-metal vanadate (M=Sr, Ag and Cd) nanocomposites. / Vignesh, K.; Hariharan, R.; Rajarajan, M.; Suganthi, A.

In: Materials Science in Semiconductor Processing, Vol. 16, No. 6, 2013, p. 1521-1530.

Research output: Contribution to journalArticle

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