Uranium isotopic ratio measurements of U3O8 reference materials by atom probe tomography

Albert J. Fahey, Daniel E. Perea, Jonah Bartrand, Bruce W. Arey, Suntharampillai Thevuthasan

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We report results of measurements of isotopic ratios obtained with atom probe tomography on U3O8 reference materials certified for their isotopic abundances of uranium. The results show good agreement with the certified values. High backgrounds due to tails from adjacent peaks complicate the measurement of the integrated peak areas as well as the fact that only oxides of uranium appear in the spectrum, the most intense of which is doubly charged. In addition, lack of knowledge of other instrumental parameters, such as the dead time, may bias the results. Isotopic ratio measurements can be performed at the nanometer-scale with the expectation of sensible results. The abundance sensitivity and mass resolving power of the mass spectrometer are not sufficient to compete with magnetic-sector instruments but are not far from measurements made by ToF-SIMS of other isotopic systems. The agreement of the major isotope ratios is more than sufficient to distinguish most anthropogenic compositions from natural.

Original languageEnglish
Pages (from-to)206-213
Number of pages8
JournalJournal of Environmental Radioactivity
Volume153
DOIs
Publication statusPublished - 1 Mar 2016
Externally publishedYes

Fingerprint

Uranium
isotopic ratio
Isotopes
tomography
Tomography
uranium
probe
Atoms
spectrometer
oxide
isotope
Optical resolving power
Mass spectrometers
Secondary ion mass spectrometry
Oxides
material
uranium octoxide
uranium oxide
Chemical analysis
parameter

Keywords

  • Atom probe tomography
  • Isotopic ratios
  • Uranium

ASJC Scopus subject areas

  • Environmental Chemistry
  • Health, Toxicology and Mutagenesis
  • Waste Management and Disposal
  • Pollution

Cite this

Uranium isotopic ratio measurements of U3O8 reference materials by atom probe tomography. / Fahey, Albert J.; Perea, Daniel E.; Bartrand, Jonah; Arey, Bruce W.; Thevuthasan, Suntharampillai.

In: Journal of Environmental Radioactivity, Vol. 153, 01.03.2016, p. 206-213.

Research output: Contribution to journalArticle

Fahey, Albert J. ; Perea, Daniel E. ; Bartrand, Jonah ; Arey, Bruce W. ; Thevuthasan, Suntharampillai. / Uranium isotopic ratio measurements of U3O8 reference materials by atom probe tomography. In: Journal of Environmental Radioactivity. 2016 ; Vol. 153. pp. 206-213.
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