Understanding the origin of the ultrahigh rate performance of a SiO2-Modified LiNi0.5Mn1.5O4 cathode for lithium-ion batteries

Umair Nisar, Sara Ahmad J.A. Al-Hail, Ramesh Kumar Petla, R. A. Shakoor, Rachid Essehli, Ramazan Kahraman, Siham Y. Alqaradawi, Do Kyung Kim, Ilias Belharouak, Md Ruhul Amin

Research output: Contribution to journalArticle

Abstract

LiNi0.5Mn1.5O4 (LNMO) is one of the most promising cathode materials for next-generation lithium-ion batteries for rapid charging-discharging applications. The surfaces of LNMO samples are coated with different amounts (0.5-2.0 wt %) of silica (SiO2) using a cost-effective and scalable ball milling process, and the surface-modified samples shows excellent electrochemical stability with conventional liquid electrolyte. The advantages of this coating are demonstrated by the improved electrochemical performances at ambient and elevated temperatures (25 and 55 °C) using half- and full-cell configurations. The solid electrolyte interface (SEI) and coating properties have been highlighted by ex situ TEM analysis, which indicates the close attachment and good wetting of the SiO2 layer with the LNMO active particles. Importantly, the 1 wt % SiO2-coated material cycled at 10, 40, and 80 C rates for 400 cycles exhibits excellent cycling stability with capacity retentions of 96.7, 87.9, and 82.4%, respectively. The 1 wt % SiO2-coated material also shows excellent cycling stability when charged at 6 C (10 min.) and discharged at C/3 for 500 cycles. The interfacial resistances of the SiO2-coated LiNi0.5Mn1.5O4 is found to be much lower compared to bare material and does not considerably increase with the amount of coating. Overall, the scalable and cost-effective strategy of SiO2 coating applied to LiNi0.5Mn1.5O4 lowers the interfacial charge transfer resistance and enables the materials to be suitable for extremely fast-charging electric vehicle battery applications.

Original languageEnglish
JournalACS Applied Energy Materials
DOIs
Publication statusAccepted/In press - 1 Jan 2019

Fingerprint

Cathodes
Coated materials
Coatings
Solid electrolytes
Ball milling
Silicon Dioxide
Electrolytes
Wetting
Charge transfer
Costs
Silica
Transmission electron microscopy
Lithium-ion batteries
Liquids
Temperature

Keywords

  • electric vehicles
  • lithium-ion batteries
  • SiO coating
  • solid electrolyte interface (SEI) layer
  • spinel LiNiMnO

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrochemistry
  • Materials Chemistry
  • Electrical and Electronic Engineering

Cite this

Understanding the origin of the ultrahigh rate performance of a SiO2-Modified LiNi0.5Mn1.5O4 cathode for lithium-ion batteries. / Nisar, Umair; Al-Hail, Sara Ahmad J.A.; Petla, Ramesh Kumar; Shakoor, R. A.; Essehli, Rachid; Kahraman, Ramazan; Alqaradawi, Siham Y.; Kim, Do Kyung; Belharouak, Ilias; Amin, Md Ruhul.

In: ACS Applied Energy Materials, 01.01.2019.

Research output: Contribution to journalArticle

Nisar, Umair ; Al-Hail, Sara Ahmad J.A. ; Petla, Ramesh Kumar ; Shakoor, R. A. ; Essehli, Rachid ; Kahraman, Ramazan ; Alqaradawi, Siham Y. ; Kim, Do Kyung ; Belharouak, Ilias ; Amin, Md Ruhul. / Understanding the origin of the ultrahigh rate performance of a SiO2-Modified LiNi0.5Mn1.5O4 cathode for lithium-ion batteries. In: ACS Applied Energy Materials. 2019.
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title = "Understanding the origin of the ultrahigh rate performance of a SiO2-Modified LiNi0.5Mn1.5O4 cathode for lithium-ion batteries",
abstract = "LiNi0.5Mn1.5O4 (LNMO) is one of the most promising cathode materials for next-generation lithium-ion batteries for rapid charging-discharging applications. The surfaces of LNMO samples are coated with different amounts (0.5-2.0 wt {\%}) of silica (SiO2) using a cost-effective and scalable ball milling process, and the surface-modified samples shows excellent electrochemical stability with conventional liquid electrolyte. The advantages of this coating are demonstrated by the improved electrochemical performances at ambient and elevated temperatures (25 and 55 °C) using half- and full-cell configurations. The solid electrolyte interface (SEI) and coating properties have been highlighted by ex situ TEM analysis, which indicates the close attachment and good wetting of the SiO2 layer with the LNMO active particles. Importantly, the 1 wt {\%} SiO2-coated material cycled at 10, 40, and 80 C rates for 400 cycles exhibits excellent cycling stability with capacity retentions of 96.7, 87.9, and 82.4{\%}, respectively. The 1 wt {\%} SiO2-coated material also shows excellent cycling stability when charged at 6 C (10 min.) and discharged at C/3 for 500 cycles. The interfacial resistances of the SiO2-coated LiNi0.5Mn1.5O4 is found to be much lower compared to bare material and does not considerably increase with the amount of coating. Overall, the scalable and cost-effective strategy of SiO2 coating applied to LiNi0.5Mn1.5O4 lowers the interfacial charge transfer resistance and enables the materials to be suitable for extremely fast-charging electric vehicle battery applications.",
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T1 - Understanding the origin of the ultrahigh rate performance of a SiO2-Modified LiNi0.5Mn1.5O4 cathode for lithium-ion batteries

AU - Nisar, Umair

AU - Al-Hail, Sara Ahmad J.A.

AU - Petla, Ramesh Kumar

AU - Shakoor, R. A.

AU - Essehli, Rachid

AU - Kahraman, Ramazan

AU - Alqaradawi, Siham Y.

AU - Kim, Do Kyung

AU - Belharouak, Ilias

AU - Amin, Md Ruhul

PY - 2019/1/1

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N2 - LiNi0.5Mn1.5O4 (LNMO) is one of the most promising cathode materials for next-generation lithium-ion batteries for rapid charging-discharging applications. The surfaces of LNMO samples are coated with different amounts (0.5-2.0 wt %) of silica (SiO2) using a cost-effective and scalable ball milling process, and the surface-modified samples shows excellent electrochemical stability with conventional liquid electrolyte. The advantages of this coating are demonstrated by the improved electrochemical performances at ambient and elevated temperatures (25 and 55 °C) using half- and full-cell configurations. The solid electrolyte interface (SEI) and coating properties have been highlighted by ex situ TEM analysis, which indicates the close attachment and good wetting of the SiO2 layer with the LNMO active particles. Importantly, the 1 wt % SiO2-coated material cycled at 10, 40, and 80 C rates for 400 cycles exhibits excellent cycling stability with capacity retentions of 96.7, 87.9, and 82.4%, respectively. The 1 wt % SiO2-coated material also shows excellent cycling stability when charged at 6 C (10 min.) and discharged at C/3 for 500 cycles. The interfacial resistances of the SiO2-coated LiNi0.5Mn1.5O4 is found to be much lower compared to bare material and does not considerably increase with the amount of coating. Overall, the scalable and cost-effective strategy of SiO2 coating applied to LiNi0.5Mn1.5O4 lowers the interfacial charge transfer resistance and enables the materials to be suitable for extremely fast-charging electric vehicle battery applications.

AB - LiNi0.5Mn1.5O4 (LNMO) is one of the most promising cathode materials for next-generation lithium-ion batteries for rapid charging-discharging applications. The surfaces of LNMO samples are coated with different amounts (0.5-2.0 wt %) of silica (SiO2) using a cost-effective and scalable ball milling process, and the surface-modified samples shows excellent electrochemical stability with conventional liquid electrolyte. The advantages of this coating are demonstrated by the improved electrochemical performances at ambient and elevated temperatures (25 and 55 °C) using half- and full-cell configurations. The solid electrolyte interface (SEI) and coating properties have been highlighted by ex situ TEM analysis, which indicates the close attachment and good wetting of the SiO2 layer with the LNMO active particles. Importantly, the 1 wt % SiO2-coated material cycled at 10, 40, and 80 C rates for 400 cycles exhibits excellent cycling stability with capacity retentions of 96.7, 87.9, and 82.4%, respectively. The 1 wt % SiO2-coated material also shows excellent cycling stability when charged at 6 C (10 min.) and discharged at C/3 for 500 cycles. The interfacial resistances of the SiO2-coated LiNi0.5Mn1.5O4 is found to be much lower compared to bare material and does not considerably increase with the amount of coating. Overall, the scalable and cost-effective strategy of SiO2 coating applied to LiNi0.5Mn1.5O4 lowers the interfacial charge transfer resistance and enables the materials to be suitable for extremely fast-charging electric vehicle battery applications.

KW - electric vehicles

KW - lithium-ion batteries

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KW - solid electrolyte interface (SEI) layer

KW - spinel LiNiMnO

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