Transformation of 1,1,2,2-tetrachloroethane and trichloroethylene in Fe(II)-based degradative solidification/stabilization

Bahngmi Jung, Bill Batchelor

Research output: Contribution to journalArticle

Abstract

Iron-based degradative solidification/stabilization (DS/S-Fe(II)) technology is an attractive treatment method that combines a chemical degradation process by Fe(II) with conventional solidification/stabilization. The effectiveness of DS/S-Fe(II) has already been proven for chlorinated organics including PCE, CT, and PCB. The applicability of DS/S-Fe(II) to 1,1,1-trichloroethane (1,1,1-TCA) was studied. Degradation kinetics of 1,1,1-TCA by Fe(II) in 10% cement slurries was studied using batch slurry reactors. A saturation model observed at higher Fe(II) concentration and target organic concentration describes that reductive dechlorination of 1,1,1-TCA occurs on the surface of active solids. Reductive reaction pathway of 1,1,1-TCA was suggested through identification of transformation products of 1,1,1-TCA. This is an abstract of a paper presented at the 231th ACS National Meeting (Atlanta, GA 3/26-30/2006).

Original languageEnglish
JournalACS National Meeting Book of Abstracts
Volume231
Publication statusPublished - 2006
Externally publishedYes

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Trichloroethylene
Solidification
Stabilization
Degradation
Dechlorination
Polychlorinated Biphenyls
Slurries
Polychlorinated biphenyls
Cements
Iron
Kinetics
1,1,2,2-tetrachloroethane
1,1,1-trichloroethane

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Transformation of 1,1,2,2-tetrachloroethane and trichloroethylene in Fe(II)-based degradative solidification/stabilization",
abstract = "Iron-based degradative solidification/stabilization (DS/S-Fe(II)) technology is an attractive treatment method that combines a chemical degradation process by Fe(II) with conventional solidification/stabilization. The effectiveness of DS/S-Fe(II) has already been proven for chlorinated organics including PCE, CT, and PCB. The applicability of DS/S-Fe(II) to 1,1,1-trichloroethane (1,1,1-TCA) was studied. Degradation kinetics of 1,1,1-TCA by Fe(II) in 10{\%} cement slurries was studied using batch slurry reactors. A saturation model observed at higher Fe(II) concentration and target organic concentration describes that reductive dechlorination of 1,1,1-TCA occurs on the surface of active solids. Reductive reaction pathway of 1,1,1-TCA was suggested through identification of transformation products of 1,1,1-TCA. This is an abstract of a paper presented at the 231th ACS National Meeting (Atlanta, GA 3/26-30/2006).",
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AU - Jung, Bahngmi

AU - Batchelor, Bill

PY - 2006

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N2 - Iron-based degradative solidification/stabilization (DS/S-Fe(II)) technology is an attractive treatment method that combines a chemical degradation process by Fe(II) with conventional solidification/stabilization. The effectiveness of DS/S-Fe(II) has already been proven for chlorinated organics including PCE, CT, and PCB. The applicability of DS/S-Fe(II) to 1,1,1-trichloroethane (1,1,1-TCA) was studied. Degradation kinetics of 1,1,1-TCA by Fe(II) in 10% cement slurries was studied using batch slurry reactors. A saturation model observed at higher Fe(II) concentration and target organic concentration describes that reductive dechlorination of 1,1,1-TCA occurs on the surface of active solids. Reductive reaction pathway of 1,1,1-TCA was suggested through identification of transformation products of 1,1,1-TCA. This is an abstract of a paper presented at the 231th ACS National Meeting (Atlanta, GA 3/26-30/2006).

AB - Iron-based degradative solidification/stabilization (DS/S-Fe(II)) technology is an attractive treatment method that combines a chemical degradation process by Fe(II) with conventional solidification/stabilization. The effectiveness of DS/S-Fe(II) has already been proven for chlorinated organics including PCE, CT, and PCB. The applicability of DS/S-Fe(II) to 1,1,1-trichloroethane (1,1,1-TCA) was studied. Degradation kinetics of 1,1,1-TCA by Fe(II) in 10% cement slurries was studied using batch slurry reactors. A saturation model observed at higher Fe(II) concentration and target organic concentration describes that reductive dechlorination of 1,1,1-TCA occurs on the surface of active solids. Reductive reaction pathway of 1,1,1-TCA was suggested through identification of transformation products of 1,1,1-TCA. This is an abstract of a paper presented at the 231th ACS National Meeting (Atlanta, GA 3/26-30/2006).

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