Tracer microrheology study of a hydrophobically modified comblike associative polymer

Ahmed Abdala, Samiul Amin, John H. Van Zanten, Saad A. Khan

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The viscoelastic properties of associative polymers are important not only for their use as rheology modifiers but also to understand their complex structure in aqueous media. In this study, the dynamics of comblike hydrophobically modified alkali swellable associative (HASE) polymers are probed using diffusing wave spectroscopy (DWS) based tracer microrheology. DWS-based tracer microrheology accurately probes the dynamics of HASE polymers, and the extracted microrheological moduli versus frequency profile obtained from this technique closely matches that obtained from rotational rheometry measurements. Quantitatively, however, the moduli extracted from DWS-based tracer microrheology measurements are slightly higher than those obtained using rotational rheometry. The creep compliance, elastic modulus, and relaxation time concentration scaling behavior exhibits a power-law dependence. The length scale associated with the elastic to glassy behavior change is obtained from the time-dependent diffusion coefficient. The Zimm-Rouse type scaling is recovered at high frequencies but shows a concentration effect switching from Zimm to more Rouse-like behavior at higher concentrations.

Original languageEnglish
Pages (from-to)3944-3951
Number of pages8
JournalLangmuir
Volume31
Issue number13
DOIs
Publication statusPublished - 7 Apr 2015

Fingerprint

tracers
Spectrum Analysis
Polymers
Alkalies
Spectroscopy
alkalies
polymers
spectroscopy
scaling
Rheology
Elastic Modulus
rheology
Relaxation time
Compliance
modulus of elasticity
Creep
diffusion coefficient
Elastic moduli
relaxation time
probes

ASJC Scopus subject areas

  • Electrochemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Materials Science(all)
  • Spectroscopy
  • Medicine(all)

Cite this

Tracer microrheology study of a hydrophobically modified comblike associative polymer. / Abdala, Ahmed; Amin, Samiul; Van Zanten, John H.; Khan, Saad A.

In: Langmuir, Vol. 31, No. 13, 07.04.2015, p. 3944-3951.

Research output: Contribution to journalArticle

Abdala, Ahmed ; Amin, Samiul ; Van Zanten, John H. ; Khan, Saad A. / Tracer microrheology study of a hydrophobically modified comblike associative polymer. In: Langmuir. 2015 ; Vol. 31, No. 13. pp. 3944-3951.
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