Three-dimensional porous carbon nanotube sponges for high-performance anodes of microbial fuel cells

Celal Erbay, Gang Yang, Paul De Figueiredo, Reza Sadr, Choongho Yu, Arum Han

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Highly-porous, light-weight, and inexpensive three-dimensional (3D) sponges consisting of interconnected carbon nanotubes (CNTs) without base materials are synthesized with a facile and scalable one-step chemical vapor deposition process as anode of microbial fuel cells (MFCs). The MFCs generates higher power densities of 2150 W m-3 (per anode volume) or 170 W m-3 (per anode chamber volume), comparable to those of commercial 3D carbon felt electrodes under the same conditions. The high performances are due to excellent charge transfer between CNTs and microbes owing to 13 times lower charge transfer resistance compared to that of carbon felt. The material cost of producing these CNT sponge estimates to be ∼$0.1/gCNT, significantly lower than that of other methods. In addition, the high production rate of about 3.6 g h-1 compared to typical production rate of 0.02 g h-1 of other CNT-based materials makes this process economically viable. The one-step synthesis method allowing self-assembly of 3D CNT sponges as they grow is low cost and scalable, making this a promising method for manufacturing high-performance anodes of MFCs, with broad applicability to microbial electrochemical systems in general.

Original languageEnglish
Pages (from-to)177-183
Number of pages7
JournalJournal of Power Sources
Volume298
DOIs
Publication statusPublished - 1 Dec 2015

Fingerprint

Microbial fuel cells
Carbon Nanotubes
fuel cells
Carbon nanotubes
Anodes
anodes
carbon nanotubes
Charge transfer
charge transfer
Carbon
carbon
microorganisms
Self assembly
self assembly
radiant flux density
Costs
Chemical vapor deposition
manufacturing
chambers
vapor deposition

Keywords

  • Carbon nanotube sponge
  • Microbial fuel cell
  • One-step synthesis
  • Three dimensional electrodes

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Physical and Theoretical Chemistry

Cite this

Three-dimensional porous carbon nanotube sponges for high-performance anodes of microbial fuel cells. / Erbay, Celal; Yang, Gang; De Figueiredo, Paul; Sadr, Reza; Yu, Choongho; Han, Arum.

In: Journal of Power Sources, Vol. 298, 01.12.2015, p. 177-183.

Research output: Contribution to journalArticle

Erbay, Celal ; Yang, Gang ; De Figueiredo, Paul ; Sadr, Reza ; Yu, Choongho ; Han, Arum. / Three-dimensional porous carbon nanotube sponges for high-performance anodes of microbial fuel cells. In: Journal of Power Sources. 2015 ; Vol. 298. pp. 177-183.
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