Thermodynamic and transport property models for carbon capture and sequestration (CCS) processes with emphasis on CO2 transport

Nikolaos I. Diamantonis, Georgios C. Boulougouris, Dimitrios M. Tsangaris, Mohamad J El Kadi, Hisham Saadawi, Shahin Negahban, Ioannis Economou

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Carbon capture and sequestration (CCS) is one of the most promising technologies for the reduction of carbon dioxide (CO2) concentration in the atmosphere, so that global warming can be controlled and eventually eliminated. A crucial part in the CCS process design is the model that is used to calculate the physical properties (thermodynamic, transport etc.) of pure CO2 and CO2 mixtures with other components.In this work, an overview of various thermodynamic models together with calculations from cubic and higher order equations of state (EoS) are provided. Calculations are compared to experimental data and a discussion on the accuracy of the models is given. The CO2 mixture properties studied include phase equilibria, density, isothermal compressibility, speed of sound, and Joule-Thomson inversion curve. The Peng-Robinson, Soave-Redlich-Kwong, and the Perturbed Chain-Statistical Associating Fluid Theory (PC-SAFT) are the EoS used for the calculations. In addition, various models for transport properties are discussed and calculations for viscosity and diffusion coefficient are presented.

Original languageEnglish
Pages (from-to)1793-1806
Number of pages14
JournalChemical Engineering Research and Design
Volume91
Issue number10
DOIs
Publication statusPublished - Oct 2013

Fingerprint

Carbon capture
Transport properties
Thermodynamic properties
Equations of state
Thermodynamics
Acoustic wave velocity
Global warming
Compressibility
Carbon Dioxide
Phase equilibria
Density (specific gravity)
Process design
Carbon dioxide
Physical properties
Viscosity
Fluids

Keywords

  • Carbon capture and sequestration
  • Carbon dioxide
  • Derivative thermodynamic properties
  • Thermodynamic models
  • Transport properties

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Thermodynamic and transport property models for carbon capture and sequestration (CCS) processes with emphasis on CO2 transport. / Diamantonis, Nikolaos I.; Boulougouris, Georgios C.; Tsangaris, Dimitrios M.; Kadi, Mohamad J El; Saadawi, Hisham; Negahban, Shahin; Economou, Ioannis.

In: Chemical Engineering Research and Design, Vol. 91, No. 10, 10.2013, p. 1793-1806.

Research output: Contribution to journalArticle

Diamantonis, Nikolaos I. ; Boulougouris, Georgios C. ; Tsangaris, Dimitrios M. ; Kadi, Mohamad J El ; Saadawi, Hisham ; Negahban, Shahin ; Economou, Ioannis. / Thermodynamic and transport property models for carbon capture and sequestration (CCS) processes with emphasis on CO2 transport. In: Chemical Engineering Research and Design. 2013 ; Vol. 91, No. 10. pp. 1793-1806.
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