The role of organic condensation on ultrafine particle growth during nucleation events

D. Patoulias, Christos Fountoukis, I. Riipinen, S. N. Pandis

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A new aerosol dynamics model (DMANx) has been developed that simulates aerosol size/composition distribution and includes the condensation of organic vapors on nanoparticles through the implementation of the recently developed volatility basis set framework. Simulations were performed for Hyytiälä (Finland) and Finokalia (Greece), two locations with different organic sources where detailed measurements were available to constrain the new model. We investigate the effect of condensation of organics and chemical aging reactions of secondary organic aerosol (SOA) precursors on ultrafine particle growth and particle number concentration during a typical springtime nucleation event in both locations. This work highlights the importance of the pathways of oxidation of biogenic volatile organic compounds and the production of extremely low volatility organics. At Hyytiälä, organic condensation dominates the growth process of new particles. The low-volatility SOA contributes to particle growth during the early growth stage, but after a few hours most of the growth is due to semi-volatile SOA. At Finokalia, simulations show that organics have a complementary role in new particle growth, contributing 45% to the total mass of new particles. Condensation of organics increases the number concentration of particles that can act as CCN (cloud condensation nuclei) (N100) by 13% at Finokalia and 25% at Hyytiälä during a typical spring day with nucleation. The sensitivity of our results to the surface tension used is discussed.

Original languageEnglish
Pages (from-to)6337-6350
Number of pages14
JournalAtmospheric Chemistry and Physics
Volume15
Issue number11
DOIs
Publication statusPublished - 11 Jun 2015
Externally publishedYes

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nucleation
condensation
aerosol
cloud condensation nucleus
surface tension
particle
simulation
volatile organic compound
particle size
oxidation
volatility

ASJC Scopus subject areas

  • Atmospheric Science

Cite this

The role of organic condensation on ultrafine particle growth during nucleation events. / Patoulias, D.; Fountoukis, Christos; Riipinen, I.; Pandis, S. N.

In: Atmospheric Chemistry and Physics, Vol. 15, No. 11, 11.06.2015, p. 6337-6350.

Research output: Contribution to journalArticle

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