The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2

Hamdi Yahia, Masahiro Shikano, Maxim Avdeev, Ilias Belharouak

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The new compound Co5(OH)6(H2O)2[SO3]2 was synthesized by a hydrothermal route and its crystal structure was determined from the combination of single crystal X-ray- and neutron powder-diffraction data. Co5(OH)6(H2O)2[SO3]2 crystallizes with the space group P21/c, a=7.0229(19) Å, b=5.4722(15) Å, c=15.833(4), β=106.34(1)°, V=583.9(3) Å3 and Z=4. The crystal structure consists of a 2D-framework of cobalt octahedra sharing corners and edges and giving rise to a stairs-like layers, interconnected through O-H⋯O-S4+ hydrogen bonds.

Original languageEnglish
Pages (from-to)349-355
Number of pages7
JournalZeitschrift fur Kristallographie - Crystalline Materials
Volume232
Issue number5
DOIs
Publication statusPublished - 1 May 2017

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Stairs
Crystal structure
crystal structure
Neutron powder diffraction
Cobalt
Hydrogen bonds
cobalt
routes
Single crystals
hydrogen bonds
neutrons
X rays
single crystals
diffraction
x rays

Keywords

  • crystal structure
  • hydrothermal synthesis
  • layered compound
  • sulfite compound

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2 . / Yahia, Hamdi; Shikano, Masahiro; Avdeev, Maxim; Belharouak, Ilias.

In: Zeitschrift fur Kristallographie - Crystalline Materials, Vol. 232, No. 5, 01.05.2017, p. 349-355.

Research output: Contribution to journalArticle

Yahia, Hamdi ; Shikano, Masahiro ; Avdeev, Maxim ; Belharouak, Ilias. / The novel stairs-like layered compound Co5(OH)6(H2O)2[SO3]2 In: Zeitschrift fur Kristallographie - Crystalline Materials. 2017 ; Vol. 232, No. 5. pp. 349-355.
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