The Lewis basicity of the [Pt3(μ‐CO)3(PR3)3] clusters and the X‐ray crystal structure of [{ZnI2}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}]

Andreas Stockhammer, Klaus‐Hermann ‐H Dahmen, Tobias Gerfin, Luigi M. Venanzi, Volker Gramlich, Walter Fetter

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

The cluster compounds [Pt3(μ‐CO)3(PR3)3] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX2, and Group XIII, MX3, to form cluster compounds of the composition [{MXn}{Pt3(μ‐CO)3(PR3)3}]. The X‐ray crystal structure, NMR and IR data are given for the compound [{ZnI}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}].

Original languageEnglish
Pages (from-to)989-992
Number of pages4
JournalHelvetica Chimica Acta
Volume74
Issue number5
DOIs
Publication statusPublished - 1991
Externally publishedYes

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Lewis Bases
Metal halides
Alkalinity
Crystal structure
Metals
Nuclear magnetic resonance
X-Rays
crystal structure
Chemical analysis
Lewis base
metal halides
nuclear magnetic resonance

ASJC Scopus subject areas

  • Catalysis
  • Biochemistry
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

The Lewis basicity of the [Pt3(μ‐CO)3(PR3)3] clusters and the X‐ray crystal structure of [{ZnI2}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}]. / Stockhammer, Andreas; Dahmen, Klaus‐Hermann ‐H; Gerfin, Tobias; Venanzi, Luigi M.; Gramlich, Volker; Fetter, Walter.

In: Helvetica Chimica Acta, Vol. 74, No. 5, 1991, p. 989-992.

Research output: Contribution to journalArticle

Stockhammer, Andreas ; Dahmen, Klaus‐Hermann ‐H ; Gerfin, Tobias ; Venanzi, Luigi M. ; Gramlich, Volker ; Fetter, Walter. / The Lewis basicity of the [Pt3(μ‐CO)3(PR3)3] clusters and the X‐ray crystal structure of [{ZnI2}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}]. In: Helvetica Chimica Acta. 1991 ; Vol. 74, No. 5. pp. 989-992.
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abstract = "The cluster compounds [Pt3(μ‐CO)3(PR3)3] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX2, and Group XIII, MX3, to form cluster compounds of the composition [{MXn}{Pt3(μ‐CO)3(PR3)3}]. The X‐ray crystal structure, NMR and IR data are given for the compound [{ZnI}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}].",
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