The Lewis basicity of the [Pt3(μ‐CO)3(PR3)3] clusters and the X‐ray crystal structure of [{ZnI2}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}]

Andreas Stockhammer, Klaus‐Hermann ‐H Dahmen, Tobias Gerfin, Luigi M. Venanzi, Volker Gramlich, Walter Fetter

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Abstract

The cluster compounds [Pt3(μ‐CO)3(PR3)3] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX2, and Group XIII, MX3, to form cluster compounds of the composition [{MXn}{Pt3(μ‐CO)3(PR3)3}]. The X‐ray crystal structure, NMR and IR data are given for the compound [{ZnI}{Pt3(μ‐CO)3(PPh(i‐Pr)2)3}].

Original languageEnglish
Pages (from-to)989-992
Number of pages4
JournalHelvetica Chimica Acta
Volume74
Issue number5
DOIs
Publication statusPublished - 1991
Externally publishedYes

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ASJC Scopus subject areas

  • Catalysis
  • Biochemistry
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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