Synthesis of ferrocenoyl L-arginine derivatives by homogeneous catalytic carbonylation

János Balogh, Zoltán Berente, Dávid Frigyes, László Kollár, Rita Skoda-Földes

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Abstract

Ferrocene-labeled arginine derivatives with different structures were synthesized via homogeneous catalytic carbonylation. Aminocarbonylation of iodoferrocene in the presence of L-arginine methyl ester or N α-benzoyl-L-arginine ethyl ester as N-nucleophiles led to triacyl derivatives as the main products. The formation of diacyl compounds was also observed, but no monoacyl derivative could be isolated from the reaction mixture of iodoferrocene and L-arginine methyl ester.

Original languageEnglish
Pages (from-to)887-895
Number of pages9
JournalSynthetic Communications
Volume39
Issue number5
DOIs
Publication statusPublished - Jan 2009
Externally publishedYes

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Keywords

  • Carbonylation
  • Ferrocene
  • L-arginine
  • Palladium

ASJC Scopus subject areas

  • Organic Chemistry

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