Synthesis of Aliphatic Acids from CO2 and Water at Efficiencies Close to the Photosynthesis Limit Using Mixed Copper and Iron Oxide Films

Unseock Kang, Sun Hee Yoon, Dong Suk Han, Hyunwoong Park

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The photocatalytic conversion of CO2 and water into value-added chemicals remains a great challenge. This study shows that uniformly mixed copper and iron oxide (CuO/CuFeO2; CFO) bulky heterojunction films are capable of converting CO2 and water into C1-C6 aliphatic acid anions and O2 at a solar-to-chemical energy conversion (STC) efficiency close to 3% under simulated sunlight in the absence of any sacrificial chemicals or electrical biases. When the CFO film is simply wired to a Pt foil, C1 (formate, with selectivity of 100%) and O2 are produced at a near-stoichiometric ratio at an STC efficiency of -5% via the Z-scheme charge transfer mechanism. The CFO films are durable over 1 week and recyclable over 5 weeks under continuous irradiation. The addition of chloride enhances formate production, with an STC efficiency of 10%, while inhibiting the deformation of CFOs. Density functional theory computations support the observed selectivity and durability.

Original languageEnglish
Pages (from-to)2075-2080
Number of pages6
JournalACS Energy Letters
DOIs
Publication statusAccepted/In press - 1 Jan 2019

Fingerprint

Copper oxides
Photosynthesis
Iron oxides
formic acid
Oxide films
Fatty Acids
Energy conversion
Acids
Water
Conversion efficiency
Metal foil
Density functional theory
Anions
Heterojunctions
Charge transfer
Chlorides
Durability
Negative ions
CuFe2O4
Irradiation

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

Cite this

Synthesis of Aliphatic Acids from CO2 and Water at Efficiencies Close to the Photosynthesis Limit Using Mixed Copper and Iron Oxide Films. / Kang, Unseock; Yoon, Sun Hee; Han, Dong Suk; Park, Hyunwoong.

In: ACS Energy Letters, 01.01.2019, p. 2075-2080.

Research output: Contribution to journalArticle

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