Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4

Hamdi Yahia, Etienne Gaudin, Jacques Darriet, Michael Banks, Reinhard K. Kremer, Antoine Villesuzanne, Myung Hwan Whangbo

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

A new magnetic oxide, CuMnVO4, was prepared, and its crystal structure was determined by single-crystal X-ray diffraction. The magnetic properties of CuMnVO4 were characterized by magnetic susceptibility and specific heat measurements, and the spin exchange interactions of CuMnVO4 were analyzed on the basis of spin-polarized electronic band structure calculations. CuMnVO4 contains MnO4 chains made up of edge-sharing MnO4 octahedra containing high-spin Mn 2+ cations. Our work shows that CuMnVO4 undergoes a three-dimensional antiferromagnetic transition at ∼20 K. Both the intrachain and interchain spin exchanges are antiferromagnetic, and the interchain spin exchange is not negligible compared to the intrachain spin exchange.

Original languageEnglish
Pages (from-to)3087-3093
Number of pages7
JournalInorganic Chemistry
Volume44
Issue number9
DOIs
Publication statusPublished - 2 May 2005
Externally publishedYes

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Vanadates
vanadates
spin exchange
Electronic structure
Magnetic properties
Crystal structure
electronic structure
magnetic properties
Thermal variables measurement
crystal structure
Exchange interactions
synthesis
Magnetic susceptibility
X-Ray Diffraction
Band structure
Oxides
Specific heat
Cations
Hot Temperature
Single crystals

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Yahia, H., Gaudin, E., Darriet, J., Banks, M., Kremer, R. K., Villesuzanne, A., & Whangbo, M. H. (2005). Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4. Inorganic Chemistry, 44(9), 3087-3093. https://doi.org/10.1021/ic048244y

Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4. / Yahia, Hamdi; Gaudin, Etienne; Darriet, Jacques; Banks, Michael; Kremer, Reinhard K.; Villesuzanne, Antoine; Whangbo, Myung Hwan.

In: Inorganic Chemistry, Vol. 44, No. 9, 02.05.2005, p. 3087-3093.

Research output: Contribution to journalArticle

Yahia, H, Gaudin, E, Darriet, J, Banks, M, Kremer, RK, Villesuzanne, A & Whangbo, MH 2005, 'Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4', Inorganic Chemistry, vol. 44, no. 9, pp. 3087-3093. https://doi.org/10.1021/ic048244y
Yahia, Hamdi ; Gaudin, Etienne ; Darriet, Jacques ; Banks, Michael ; Kremer, Reinhard K. ; Villesuzanne, Antoine ; Whangbo, Myung Hwan. / Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4. In: Inorganic Chemistry. 2005 ; Vol. 44, No. 9. pp. 3087-3093.
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