Synthesis and photocatalytic activity of mesoporous nanocrystalline Fe-doped titanium dioxide

M. Qamar, Belabbes Merzougui, D. Anjum, A. S. Hakeem, Z. H. Yamani, D. Bahnemann

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Synthesis of mesoporous nanocrystalline iron-doped titania following the sol-gel method is presented in this work. Samples with various molar ratios (0.1, 0.25, 0.5, 1.0, 2.5, 5.0, 10 and 20%) of Fe to Ti were prepared. The particle size was found to be in the range of ∼12 nm while mesopores were approximately near to ∼5.5 nm. The effect of Fe as doping element on titania properties, such as crystallite size, surface area, pore size, pore volume and d-spacing was investigated. Moreover, distribution of Fe in TiO2 matrix was determined by elemental mapping whereas change in absorption properties was evaluated by diffuse reflectance spectroscopy. It was observed that as the Fe content was increased, a partial phase transformation from anatase to rutile and pseudorutile took place. Effect of ultraviolet, ultraviolet-visible and visible radiations on the photocatalytic activity of these catalysts was studied by removal of Methyl Orange as model pollutant. As results, it was found that the photocatalytic activity of such catalysts depends strongly on Fe amount and type of radiation.

Original languageEnglish
Pages (from-to)158-165
Number of pages8
JournalCatalysis Today
Volume230
DOIs
Publication statusPublished - 2014
Externally publishedYes

Fingerprint

Titanium dioxide
Thermodynamic properties
Titanium
Radiation
Catalysts
Crystallite size
Chemical elements
Sol-gel process
Pore size
Phase transitions
Particle size
Doping (additives)
Spectroscopy
Iron
titanium dioxide

Keywords

  • Mesoporous nanomaterials
  • Nanocomposite
  • Photocatalysis
  • Sol-gel
  • Visible light photocatalysts

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Synthesis and photocatalytic activity of mesoporous nanocrystalline Fe-doped titanium dioxide. / Qamar, M.; Merzougui, Belabbes; Anjum, D.; Hakeem, A. S.; Yamani, Z. H.; Bahnemann, D.

In: Catalysis Today, Vol. 230, 2014, p. 158-165.

Research output: Contribution to journalArticle

Qamar, M. ; Merzougui, Belabbes ; Anjum, D. ; Hakeem, A. S. ; Yamani, Z. H. ; Bahnemann, D. / Synthesis and photocatalytic activity of mesoporous nanocrystalline Fe-doped titanium dioxide. In: Catalysis Today. 2014 ; Vol. 230. pp. 158-165.
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