Synthesis and electrochemical investigation of oligomeric and polymeric ferrocenyl-amides having cyclohexyl, phenylene, and lysyl spacers

Khaled Mahmoud, Heinz Bernhard Kraatz

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

This paper discusses the synthesis and characterization of a series of ferrocene oligo- and polyamides having phenylene, cyclohexyl, or lysyl spacer groups separating the electroactive ferrocene groups. The oligomeric materials are characterized by spectroscopic means and display an electrochemical signature indicating very limited electronic communication between the ferrocenes. The ferrocene-phenylene polymer however, shows clear indications of weak electronic interactions.

Original languageEnglish
Pages (from-to)69-80
Number of pages12
JournalJournal of Inorganic and Organometallic Polymers and Materials
Volume18
Issue number1
DOIs
Publication statusPublished - 1 Mar 2008
Externally publishedYes

Fingerprint

Polyamides
Amides
Communication
Polymers
Nylons
ferrocene

Keywords

  • Electrochemistry
  • Ferrocene
  • Ferrocenediamine
  • Polymer

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics

Cite this

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AB - This paper discusses the synthesis and characterization of a series of ferrocene oligo- and polyamides having phenylene, cyclohexyl, or lysyl spacer groups separating the electroactive ferrocene groups. The oligomeric materials are characterized by spectroscopic means and display an electrochemical signature indicating very limited electronic communication between the ferrocenes. The ferrocene-phenylene polymer however, shows clear indications of weak electronic interactions.

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KW - Ferrocenediamine

KW - Polymer

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