Abstract
Reactions of [Pt3(μ-CO)3(PCy3)3] (1) and [Pt3(μ-CNXyl)2(μ-CO)(CNXyl)(PCy3) 2] (2) (Cy = C6H11, Xyl = C8H9) with 1/2 equiv of a bifunctional metal phosphine cation [(MPR′2)2(R)]2+ (M = Cu, Ag, Au; R = C6H4, (CH2)2C6H4, Fe(C5H5); R′ = C6H5, C6H11) yielded quantitatively [{Pt3(μ-CO)3(PCy3)3} 2{(MPR′2)2 (R)}]2+ and [(Pt3(μ-CNXyl)2-(μ-CO)(CNXyl)(PCy3) 2}2{(MPR′2)2(R)}] 2+, respectively. The compounds were characterized by IR-, MS-, and 31P-NMR spectroscopy. The X-ray structure is given for [{Pt3(μ-CO)3(PCy3)3} 2{(AuPPh2)2(CH2)2C 6H4)}][PF6]2 (14), which crystallizes in the triclinic space group P1̄ with Z= 1, a = 15.350 Å. b = 17.150 Å, c = 20.446 Å, α = 84.54°, β= 84.84°, and γ = 64.56°. The structure was refined to R = 0.0435 for the 8430 observed reflections (I > 3σ(I)).
Original language | English |
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Pages (from-to) | 1813-1820 |
Number of pages | 8 |
Journal | Inorganic Chemistry |
Volume | 36 |
Issue number | 9 |
Publication status | Published - 23 Apr 1997 |
Externally published | Yes |
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ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Synthesis and Crystal Structure Determination of Bifunctional Phosphine-Linked Triplatinum Double-Cluster Complexes. / Imhof, Daniel; Burckhardt, Urs; Dahmen, Klaus Hermann; Joho, Felix; Nesper, Reinhard.
In: Inorganic Chemistry, Vol. 36, No. 9, 23.04.1997, p. 1813-1820.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and Crystal Structure Determination of Bifunctional Phosphine-Linked Triplatinum Double-Cluster Complexes
AU - Imhof, Daniel
AU - Burckhardt, Urs
AU - Dahmen, Klaus Hermann
AU - Joho, Felix
AU - Nesper, Reinhard
PY - 1997/4/23
Y1 - 1997/4/23
N2 - Reactions of [Pt3(μ-CO)3(PCy3)3] (1) and [Pt3(μ-CNXyl)2(μ-CO)(CNXyl)(PCy3) 2] (2) (Cy = C6H11, Xyl = C8H9) with 1/2 equiv of a bifunctional metal phosphine cation [(MPR′2)2(R)]2+ (M = Cu, Ag, Au; R = C6H4, (CH2)2C6H4, Fe(C5H5); R′ = C6H5, C6H11) yielded quantitatively [{Pt3(μ-CO)3(PCy3)3} 2{(MPR′2)2 (R)}]2+ and [(Pt3(μ-CNXyl)2-(μ-CO)(CNXyl)(PCy3) 2}2{(MPR′2)2(R)}] 2+, respectively. The compounds were characterized by IR-, MS-, and 31P-NMR spectroscopy. The X-ray structure is given for [{Pt3(μ-CO)3(PCy3)3} 2{(AuPPh2)2(CH2)2C 6H4)}][PF6]2 (14), which crystallizes in the triclinic space group P1̄ with Z= 1, a = 15.350 Å. b = 17.150 Å, c = 20.446 Å, α = 84.54°, β= 84.84°, and γ = 64.56°. The structure was refined to R = 0.0435 for the 8430 observed reflections (I > 3σ(I)).
AB - Reactions of [Pt3(μ-CO)3(PCy3)3] (1) and [Pt3(μ-CNXyl)2(μ-CO)(CNXyl)(PCy3) 2] (2) (Cy = C6H11, Xyl = C8H9) with 1/2 equiv of a bifunctional metal phosphine cation [(MPR′2)2(R)]2+ (M = Cu, Ag, Au; R = C6H4, (CH2)2C6H4, Fe(C5H5); R′ = C6H5, C6H11) yielded quantitatively [{Pt3(μ-CO)3(PCy3)3} 2{(MPR′2)2 (R)}]2+ and [(Pt3(μ-CNXyl)2-(μ-CO)(CNXyl)(PCy3) 2}2{(MPR′2)2(R)}] 2+, respectively. The compounds were characterized by IR-, MS-, and 31P-NMR spectroscopy. The X-ray structure is given for [{Pt3(μ-CO)3(PCy3)3} 2{(AuPPh2)2(CH2)2C 6H4)}][PF6]2 (14), which crystallizes in the triclinic space group P1̄ with Z= 1, a = 15.350 Å. b = 17.150 Å, c = 20.446 Å, α = 84.54°, β= 84.84°, and γ = 64.56°. The structure was refined to R = 0.0435 for the 8430 observed reflections (I > 3σ(I)).
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M3 - Article
AN - SCOPUS:0000488887
VL - 36
SP - 1813
EP - 1820
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 9
ER -