Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application

J. Liu, A. Kahaian, I. Belharouak, D. Vissers, G. Henriksen, T. R. Jow, K. Amine

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Lithium ion batteries using stabilized and unstabilize lithium manganese oxide spinel were investigated in a new electrolyte that contained lithium bisoxalatoborate, LiB(C 2O 4) 2 (acronym LiBOB) salt. It was confirmed by high temperature storage tests that Mn-dissolution from the spinel was greatly reduced in the LiBOB electrolyte than in the case of LiPF 6 electrolyte Electrochemical tests show that the capacity fading in spinel/graphite cells is improved by using LiBOB electrolyte at elevated temperature, for the reason that no HF can be generated in this electrolyte. The results of this work clearly indicate that at elevated temperatures, the spinel based Li-ion cell performance characteristics are limited by the impedance rise in the graphite electrode, and that this rise is associated with the presence of dissolved manganese in the electrolyte. The Li-ion cells using a stabilized lithium manganese oxide spinel, LiBOB electrolyte, and graphite as cathode, electrolyte and anode, respectively, had much lower levels of Mn dissolved in the electrolyte, improved high temperature cycle life and excellent power capabilities for hybrid electric vehicle applications.

Original languageEnglish
Title of host publicationProceedings - Electrochemical Society
EditorsA.B. Landgrebe, T.Q. Duong, A.J. Salkind, K. Zaghib, V.S. Battaglia, Z. Ogumi, I.B. Weinstock
Pages180-188
Number of pages9
VolumePV 2003-24
Publication statusPublished - 1 Dec 2004
Externally publishedYes
Event204th Electrochemical Society Fall Meeting - Orlando, FL, United States
Duration: 12 Oct 200316 Oct 2003

Other

Other204th Electrochemical Society Fall Meeting
CountryUnited States
CityOrlando, FL
Period12/10/0316/10/03

Fingerprint

Manganese oxide
Lithium
Electrolytes
Graphite
Lithium-ion batteries
Temperature
Graphite electrodes
Ions
Hybrid vehicles
Manganese
Life cycle
Anodes
Dissolution
Cathodes
Salts

Keywords

  • Capacity fading
  • HEV
  • High power
  • Li-ion cell
  • LiBOB
  • Lithium manganese oxide spinel
  • Mn dissolution

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Liu, J., Kahaian, A., Belharouak, I., Vissers, D., Henriksen, G., Jow, T. R., & Amine, K. (2004). Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application. In A. B. Landgrebe, T. Q. Duong, A. J. Salkind, K. Zaghib, V. S. Battaglia, Z. Ogumi, & I. B. Weinstock (Eds.), Proceedings - Electrochemical Society (Vol. PV 2003-24, pp. 180-188)

Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application. / Liu, J.; Kahaian, A.; Belharouak, I.; Vissers, D.; Henriksen, G.; Jow, T. R.; Amine, K.

Proceedings - Electrochemical Society. ed. / A.B. Landgrebe; T.Q. Duong; A.J. Salkind; K. Zaghib; V.S. Battaglia; Z. Ogumi; I.B. Weinstock. Vol. PV 2003-24 2004. p. 180-188.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Liu, J, Kahaian, A, Belharouak, I, Vissers, D, Henriksen, G, Jow, TR & Amine, K 2004, Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application. in AB Landgrebe, TQ Duong, AJ Salkind, K Zaghib, VS Battaglia, Z Ogumi & IB Weinstock (eds), Proceedings - Electrochemical Society. vol. PV 2003-24, pp. 180-188, 204th Electrochemical Society Fall Meeting, Orlando, FL, United States, 12/10/03.
Liu J, Kahaian A, Belharouak I, Vissers D, Henriksen G, Jow TR et al. Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application. In Landgrebe AB, Duong TQ, Salkind AJ, Zaghib K, Battaglia VS, Ogumi Z, Weinstock IB, editors, Proceedings - Electrochemical Society. Vol. PV 2003-24. 2004. p. 180-188
Liu, J. ; Kahaian, A. ; Belharouak, I. ; Vissers, D. ; Henriksen, G. ; Jow, T. R. ; Amine, K. / Spinel lithium manganese oxide in LiBOB electrolyte for high power li-ion battery application. Proceedings - Electrochemical Society. editor / A.B. Landgrebe ; T.Q. Duong ; A.J. Salkind ; K. Zaghib ; V.S. Battaglia ; Z. Ogumi ; I.B. Weinstock. Vol. PV 2003-24 2004. pp. 180-188
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AU - Jow, T. R.

AU - Amine, K.

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N2 - Lithium ion batteries using stabilized and unstabilize lithium manganese oxide spinel were investigated in a new electrolyte that contained lithium bisoxalatoborate, LiB(C 2O 4) 2 (acronym LiBOB) salt. It was confirmed by high temperature storage tests that Mn-dissolution from the spinel was greatly reduced in the LiBOB electrolyte than in the case of LiPF 6 electrolyte Electrochemical tests show that the capacity fading in spinel/graphite cells is improved by using LiBOB electrolyte at elevated temperature, for the reason that no HF can be generated in this electrolyte. The results of this work clearly indicate that at elevated temperatures, the spinel based Li-ion cell performance characteristics are limited by the impedance rise in the graphite electrode, and that this rise is associated with the presence of dissolved manganese in the electrolyte. The Li-ion cells using a stabilized lithium manganese oxide spinel, LiBOB electrolyte, and graphite as cathode, electrolyte and anode, respectively, had much lower levels of Mn dissolved in the electrolyte, improved high temperature cycle life and excellent power capabilities for hybrid electric vehicle applications.

AB - Lithium ion batteries using stabilized and unstabilize lithium manganese oxide spinel were investigated in a new electrolyte that contained lithium bisoxalatoborate, LiB(C 2O 4) 2 (acronym LiBOB) salt. It was confirmed by high temperature storage tests that Mn-dissolution from the spinel was greatly reduced in the LiBOB electrolyte than in the case of LiPF 6 electrolyte Electrochemical tests show that the capacity fading in spinel/graphite cells is improved by using LiBOB electrolyte at elevated temperature, for the reason that no HF can be generated in this electrolyte. The results of this work clearly indicate that at elevated temperatures, the spinel based Li-ion cell performance characteristics are limited by the impedance rise in the graphite electrode, and that this rise is associated with the presence of dissolved manganese in the electrolyte. The Li-ion cells using a stabilized lithium manganese oxide spinel, LiBOB electrolyte, and graphite as cathode, electrolyte and anode, respectively, had much lower levels of Mn dissolved in the electrolyte, improved high temperature cycle life and excellent power capabilities for hybrid electric vehicle applications.

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KW - Mn dissolution

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