Single crystal growth of the novel Mn2(OH)2SO 3, Mn2F(OH)SO3, and Mn5(OH) 4(H2O)2[SO3]2[SO 4] compounds using a hydrothermal method

Hamdi Yahia, Masahiro Shikano, Hironori Kobayashi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The new compounds Mn2(OH)2SO3, Mn 2F(OH)SO3, and Mn5(OH)4(H 2O)2[SO3]2[SO4] were synthesized using a hydrothermal route and their crystal structures were determined using single crystal X-ray diffraction data. Mn2(OH) 2SO3 and Mn2F(OH)SO3 crystallized with the space group Pnma, a = 7.3580(14), b = 10.3429(20), c = 5.7611(11) Å, Z = 4; and a = 7.413(4), b = 10.139(5), c = 5.717(3) Å, Z = 4, respectively, whereas Mn5(OH)4(H2O) 2[SO3]2[SO4] crystallized with the space group P21/m, a = 7.6117(7), b = 8.5326(7), c = 10.9273(9) Å, β = 101.6005(13)°, Z = 2. Mn2(OH) 2SO3 and Mn2F(OH)SO3 consist of a 3D-framework of manganese octahedra sharing corners and edges and giving rise to 1D-tunnels along the a axis in which are located the sulfur atoms, whereas Mn5(OH)4(H2O)2[SO3] 2[SO4] consists of a 3D-framework of MnO5, MnO6, SO3, and SO4 polyhedra. Mn 5(OH)4(H2O)2[SO3] 2[SO4] is the first transition metal mixed sulfate-sulfite inorganic compound. Bent and symmetrically bifurcated hydrogen bonds were observed in these materials.

Original languageEnglish
Pages (from-to)7158-7166
Number of pages9
JournalDalton Transactions
Volume42
Issue number19
DOIs
Publication statusPublished - 2013
Externally publishedYes

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Inorganic compounds
Sulfites
Manganese
Crystallization
Sulfur
X-Ray Diffraction
Sulfates
Transition metals
Hydrogen
Tunnels
Hydrogen bonds
Crystal structure
Metals
Single crystals
X ray diffraction
Atoms

ASJC Scopus subject areas

  • Inorganic Chemistry

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Single crystal growth of the novel Mn2(OH)2SO 3, Mn2F(OH)SO3, and Mn5(OH) 4(H2O)2[SO3]2[SO 4] compounds using a hydrothermal method. / Yahia, Hamdi; Shikano, Masahiro; Kobayashi, Hironori.

In: Dalton Transactions, Vol. 42, No. 19, 2013, p. 7158-7166.

Research output: Contribution to journalArticle

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abstract = "The new compounds Mn2(OH)2SO3, Mn 2F(OH)SO3, and Mn5(OH)4(H 2O)2[SO3]2[SO4] were synthesized using a hydrothermal route and their crystal structures were determined using single crystal X-ray diffraction data. Mn2(OH) 2SO3 and Mn2F(OH)SO3 crystallized with the space group Pnma, a = 7.3580(14), b = 10.3429(20), c = 5.7611(11) {\AA}, Z = 4; and a = 7.413(4), b = 10.139(5), c = 5.717(3) {\AA}, Z = 4, respectively, whereas Mn5(OH)4(H2O) 2[SO3]2[SO4] crystallized with the space group P21/m, a = 7.6117(7), b = 8.5326(7), c = 10.9273(9) {\AA}, β = 101.6005(13)°, Z = 2. Mn2(OH) 2SO3 and Mn2F(OH)SO3 consist of a 3D-framework of manganese octahedra sharing corners and edges and giving rise to 1D-tunnels along the a axis in which are located the sulfur atoms, whereas Mn5(OH)4(H2O)2[SO3] 2[SO4] consists of a 3D-framework of MnO5, MnO6, SO3, and SO4 polyhedra. Mn 5(OH)4(H2O)2[SO3] 2[SO4] is the first transition metal mixed sulfate-sulfite inorganic compound. Bent and symmetrically bifurcated hydrogen bonds were observed in these materials.",
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N2 - The new compounds Mn2(OH)2SO3, Mn 2F(OH)SO3, and Mn5(OH)4(H 2O)2[SO3]2[SO4] were synthesized using a hydrothermal route and their crystal structures were determined using single crystal X-ray diffraction data. Mn2(OH) 2SO3 and Mn2F(OH)SO3 crystallized with the space group Pnma, a = 7.3580(14), b = 10.3429(20), c = 5.7611(11) Å, Z = 4; and a = 7.413(4), b = 10.139(5), c = 5.717(3) Å, Z = 4, respectively, whereas Mn5(OH)4(H2O) 2[SO3]2[SO4] crystallized with the space group P21/m, a = 7.6117(7), b = 8.5326(7), c = 10.9273(9) Å, β = 101.6005(13)°, Z = 2. Mn2(OH) 2SO3 and Mn2F(OH)SO3 consist of a 3D-framework of manganese octahedra sharing corners and edges and giving rise to 1D-tunnels along the a axis in which are located the sulfur atoms, whereas Mn5(OH)4(H2O)2[SO3] 2[SO4] consists of a 3D-framework of MnO5, MnO6, SO3, and SO4 polyhedra. Mn 5(OH)4(H2O)2[SO3] 2[SO4] is the first transition metal mixed sulfate-sulfite inorganic compound. Bent and symmetrically bifurcated hydrogen bonds were observed in these materials.

AB - The new compounds Mn2(OH)2SO3, Mn 2F(OH)SO3, and Mn5(OH)4(H 2O)2[SO3]2[SO4] were synthesized using a hydrothermal route and their crystal structures were determined using single crystal X-ray diffraction data. Mn2(OH) 2SO3 and Mn2F(OH)SO3 crystallized with the space group Pnma, a = 7.3580(14), b = 10.3429(20), c = 5.7611(11) Å, Z = 4; and a = 7.413(4), b = 10.139(5), c = 5.717(3) Å, Z = 4, respectively, whereas Mn5(OH)4(H2O) 2[SO3]2[SO4] crystallized with the space group P21/m, a = 7.6117(7), b = 8.5326(7), c = 10.9273(9) Å, β = 101.6005(13)°, Z = 2. Mn2(OH) 2SO3 and Mn2F(OH)SO3 consist of a 3D-framework of manganese octahedra sharing corners and edges and giving rise to 1D-tunnels along the a axis in which are located the sulfur atoms, whereas Mn5(OH)4(H2O)2[SO3] 2[SO4] consists of a 3D-framework of MnO5, MnO6, SO3, and SO4 polyhedra. Mn 5(OH)4(H2O)2[SO3] 2[SO4] is the first transition metal mixed sulfate-sulfite inorganic compound. Bent and symmetrically bifurcated hydrogen bonds were observed in these materials.

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