Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate

Mohammed Al-Hashimi, Gopa Roy, Alice C. Sullivan, John R H Wilson

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A range of sulfides can be selectively oxidised to the corresponding sulfoxides in good yields using catalytic quantities of immobilised cerium alkyl phosphonate and either sodium bromate or tert-butyl hydroperoxide as oxidants.

Original languageEnglish
Pages (from-to)4365-4368
Number of pages4
JournalTetrahedron Letters
Volume46
Issue number25
DOIs
Publication statusPublished - 20 Jun 2005
Externally publishedYes

Fingerprint

Sulfoxides
Cerium
tert-Butylhydroperoxide
Organophosphonates
Sulfides
Oxidants
Oxidation
sodium bromate

Keywords

  • Cerium
  • Immobilised reagents
  • Oxidation
  • Phosphonate
  • Silica
  • Sulfide
  • Sulfoxide

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate. / Al-Hashimi, Mohammed; Roy, Gopa; Sullivan, Alice C.; Wilson, John R H.

In: Tetrahedron Letters, Vol. 46, No. 25, 20.06.2005, p. 4365-4368.

Research output: Contribution to journalArticle

Al-Hashimi, Mohammed ; Roy, Gopa ; Sullivan, Alice C. ; Wilson, John R H. / Selective oxidations of sulfides to sulfoxides using immobilised cerium alkyl phosphonate. In: Tetrahedron Letters. 2005 ; Vol. 46, No. 25. pp. 4365-4368.
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