Properties of a Terpolymer-Treated Soil: A 13C NMR Study

Leesa M. Smith, Ayyavu Chandramohan, Parvin Karimineghlani, Srinath Iyengar, Howard J.M. Hanley

Research output: Contribution to journalArticle

Abstract

The Young’s modulus and the secant modulus of a terpolymer-treated soil as a function of the polymer’s characteristics are discussed in the context of a more general inelastic property known as the toughness parameter. The soil chosen was a sample of the State of Qatar subsoil. The terpolymer, designated TPAM, was characterized by a backbone structure of acrylamide, anionic carboxylate, and cationic (3-acrylamidopropyl-trimethylammonium chloride) repeat units. The backbone unit ratio was estimated from 13C NMR analyses. TPAM was synthesized by straightforward NaOH hydrolyses of an acrylamide/cationic copolymer. The correlations between the NaOH molarity of the hydrolysis solution, with the corresponding ratio of the anionic and cationic units, were shown to have a significant influence on the value of the toughness parameter. It is speculated that controlling the anionic and cationic ratio of a terpolymer is a general approach to optimize the toughness parameter of treated soils. Measurements of the molecular weight of TPAM were made, and comments on the importance of this feature are given. The equivalent viscosity was also recorded. It is pointed out that the work is particularly relevant to the practical problem of subsoil pavement stabilization in which the terpolymer acts as a soil binder. Suggestions on further work are given.

LanguageEnglish
Article number5
JournalInternational Journal of Thermophysics
Volume40
Issue number1
DOIs
Publication statusPublished - 1 Jan 2019

Fingerprint

soils
toughness
nuclear magnetic resonance
hydrolysis
Qatar
pavements
carboxylates
suggestion
molecular weight
modulus of elasticity
copolymers
stabilization
chlorides
viscosity
polymers

Keywords

  • C NMR
  • ASTM tests
  • Molecular weight
  • Polyampholyte terpolymer properties
  • Subsoil stability
  • Toughness parameter
  • Viscosity
  • Young’s/secant modulus

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Properties of a Terpolymer-Treated Soil : A 13C NMR Study. / Smith, Leesa M.; Chandramohan, Ayyavu; Karimineghlani, Parvin; Iyengar, Srinath; Hanley, Howard J.M.

In: International Journal of Thermophysics, Vol. 40, No. 1, 5, 01.01.2019.

Research output: Contribution to journalArticle

Smith, Leesa M. ; Chandramohan, Ayyavu ; Karimineghlani, Parvin ; Iyengar, Srinath ; Hanley, Howard J.M. / Properties of a Terpolymer-Treated Soil : A 13C NMR Study. In: International Journal of Thermophysics. 2019 ; Vol. 40, No. 1.
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