Abstract
In this paper, hybrid organic-inorganic membranes were prepared using three different solvents and characterized. The hybrid membranes were fabricated using sol-gel technique, which had polymethyl-methacrylate (PMMA) and tetraethyl orthosilicate (TEOS) as materials, with 80/20 ratio. The thin films were then characterized using FTIR, SEM, EDX, and mapping techniques. From the preliminary characterization, hybrid membranes were found to have nano and ultra scale tight-pores ranges, which was influenced by the solvent used. The SEM images clearly show that hybrid membranes have homogenous and smooth surface. FTIR spectroscopy uncovered all the signature peaks characteristic of silicate structures in the near-surface regions. Fingerprints of Si-O-Si groups in cyclic and linear molecular substructures were also present. From DSC analysis, the Tg value of the PMMA moieties in hybrids membranes was in the order H-15-Toluene < Pure PMMA < H-15-THF < H-15-DMF. Furthermore, from TGA analysis it was found that the hybrid membranes have higher thermal stability compared with that of pure PMMA. EDX and mapping analysis showed that the composition and distribution of particles in the membranes were different and dependent on the solvents used.
| Original language | English |
|---|---|
| Pages (from-to) | 3163-3171 |
| Number of pages | 9 |
| Journal | Journal of Applied Polymer Science |
| Volume | 99 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - 15 Feb 2006 |
| Externally published | Yes |
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Keywords
- Hybrid membrane
- Inorganic-organic
- Permeability
- PMMA/TEOS
- Sol-gel
ASJC Scopus subject areas
- Polymers and Plastics
Cite this
Poly(methyl methacrylate)/SiO2 hybrid membranes : Effect of solvents on structural and thermal properties. / Zulfikar, Muhammad Ali; Mohammad, A. Wahab; Kadhum, Abdul Amir; Hilal, Nidal.
In: Journal of Applied Polymer Science, Vol. 99, No. 6, 15.02.2006, p. 3163-3171.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Poly(methyl methacrylate)/SiO2 hybrid membranes
T2 - Effect of solvents on structural and thermal properties
AU - Zulfikar, Muhammad Ali
AU - Mohammad, A. Wahab
AU - Kadhum, Abdul Amir
AU - Hilal, Nidal
PY - 2006/2/15
Y1 - 2006/2/15
N2 - In this paper, hybrid organic-inorganic membranes were prepared using three different solvents and characterized. The hybrid membranes were fabricated using sol-gel technique, which had polymethyl-methacrylate (PMMA) and tetraethyl orthosilicate (TEOS) as materials, with 80/20 ratio. The thin films were then characterized using FTIR, SEM, EDX, and mapping techniques. From the preliminary characterization, hybrid membranes were found to have nano and ultra scale tight-pores ranges, which was influenced by the solvent used. The SEM images clearly show that hybrid membranes have homogenous and smooth surface. FTIR spectroscopy uncovered all the signature peaks characteristic of silicate structures in the near-surface regions. Fingerprints of Si-O-Si groups in cyclic and linear molecular substructures were also present. From DSC analysis, the Tg value of the PMMA moieties in hybrids membranes was in the order H-15-Toluene < Pure PMMA < H-15-THF < H-15-DMF. Furthermore, from TGA analysis it was found that the hybrid membranes have higher thermal stability compared with that of pure PMMA. EDX and mapping analysis showed that the composition and distribution of particles in the membranes were different and dependent on the solvents used.
AB - In this paper, hybrid organic-inorganic membranes were prepared using three different solvents and characterized. The hybrid membranes were fabricated using sol-gel technique, which had polymethyl-methacrylate (PMMA) and tetraethyl orthosilicate (TEOS) as materials, with 80/20 ratio. The thin films were then characterized using FTIR, SEM, EDX, and mapping techniques. From the preliminary characterization, hybrid membranes were found to have nano and ultra scale tight-pores ranges, which was influenced by the solvent used. The SEM images clearly show that hybrid membranes have homogenous and smooth surface. FTIR spectroscopy uncovered all the signature peaks characteristic of silicate structures in the near-surface regions. Fingerprints of Si-O-Si groups in cyclic and linear molecular substructures were also present. From DSC analysis, the Tg value of the PMMA moieties in hybrids membranes was in the order H-15-Toluene < Pure PMMA < H-15-THF < H-15-DMF. Furthermore, from TGA analysis it was found that the hybrid membranes have higher thermal stability compared with that of pure PMMA. EDX and mapping analysis showed that the composition and distribution of particles in the membranes were different and dependent on the solvents used.
KW - Hybrid membrane
KW - Inorganic-organic
KW - Permeability
KW - PMMA/TEOS
KW - Sol-gel
UR - http://www.scopus.com/inward/record.url?scp=33644504198&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33644504198&partnerID=8YFLogxK
U2 - 10.1002/app.22862
DO - 10.1002/app.22862
M3 - Article
AN - SCOPUS:33644504198
VL - 99
SP - 3163
EP - 3171
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
SN - 0021-8995
IS - 6
ER -