Poly(Δ4,4′-dicyclopenta[2,1-b

3,4-b′] dithiophene-co-3,4-ethylenedioxythiophene): Electrochemically generated low band gap conducting copolymers

Kavithaa Loganathan, Peter G. Pickup

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A low HOMO-LUMO gap, alkene bridged bis-bithiophene (Δ 4,4′-dicyclopenta [2,1-b:3,4-b′]dithiophene) has been copolymerized with electron rich 3,4-ethylenedioxythiophene, to produce copolymers with reduced band gaps and enhanced conductivities. Electrochemical band gaps as low as 0.1 eV have been observed, but maximum conductivities were only ca. 0.3 mS cm-1. Poor matching of the HOMO energies of the two components, together with cross-conjugation at the alkene bridge appear to limit charge carrier mobilities. These results provide further evidence that the use of donor and acceptor moieties to decrease band gaps leads to materials with decreased charge carrier mobilities due to charge localization.

Original languageEnglish
Pages (from-to)41-46
Number of pages6
JournalElectrochimica Acta
Volume51
Issue number1
DOIs
Publication statusPublished - 5 Oct 2005
Externally publishedYes

Fingerprint

Energy gap
Copolymers
Carrier mobility
Alkenes
Charge carriers
Olefins
Electrons
3,4-ethylenedioxythiophene

Keywords

  • Band gap
  • Conducting polymer
  • Conductivity

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Electrochemistry

Cite this

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title = "Poly(Δ4,4′-dicyclopenta[2,1-b: 3,4-b′] dithiophene-co-3,4-ethylenedioxythiophene): Electrochemically generated low band gap conducting copolymers",
abstract = "A low HOMO-LUMO gap, alkene bridged bis-bithiophene (Δ 4,4′-dicyclopenta [2,1-b:3,4-b′]dithiophene) has been copolymerized with electron rich 3,4-ethylenedioxythiophene, to produce copolymers with reduced band gaps and enhanced conductivities. Electrochemical band gaps as low as 0.1 eV have been observed, but maximum conductivities were only ca. 0.3 mS cm-1. Poor matching of the HOMO energies of the two components, together with cross-conjugation at the alkene bridge appear to limit charge carrier mobilities. These results provide further evidence that the use of donor and acceptor moieties to decrease band gaps leads to materials with decreased charge carrier mobilities due to charge localization.",
keywords = "Band gap, Conducting polymer, Conductivity",
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T1 - Poly(Δ4,4′-dicyclopenta[2,1-b

T2 - 3,4-b′] dithiophene-co-3,4-ethylenedioxythiophene): Electrochemically generated low band gap conducting copolymers

AU - Loganathan, Kavithaa

AU - Pickup, Peter G.

PY - 2005/10/5

Y1 - 2005/10/5

N2 - A low HOMO-LUMO gap, alkene bridged bis-bithiophene (Δ 4,4′-dicyclopenta [2,1-b:3,4-b′]dithiophene) has been copolymerized with electron rich 3,4-ethylenedioxythiophene, to produce copolymers with reduced band gaps and enhanced conductivities. Electrochemical band gaps as low as 0.1 eV have been observed, but maximum conductivities were only ca. 0.3 mS cm-1. Poor matching of the HOMO energies of the two components, together with cross-conjugation at the alkene bridge appear to limit charge carrier mobilities. These results provide further evidence that the use of donor and acceptor moieties to decrease band gaps leads to materials with decreased charge carrier mobilities due to charge localization.

AB - A low HOMO-LUMO gap, alkene bridged bis-bithiophene (Δ 4,4′-dicyclopenta [2,1-b:3,4-b′]dithiophene) has been copolymerized with electron rich 3,4-ethylenedioxythiophene, to produce copolymers with reduced band gaps and enhanced conductivities. Electrochemical band gaps as low as 0.1 eV have been observed, but maximum conductivities were only ca. 0.3 mS cm-1. Poor matching of the HOMO energies of the two components, together with cross-conjugation at the alkene bridge appear to limit charge carrier mobilities. These results provide further evidence that the use of donor and acceptor moieties to decrease band gaps leads to materials with decreased charge carrier mobilities due to charge localization.

KW - Band gap

KW - Conducting polymer

KW - Conductivity

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