Considering the photoionization of a two-layer fullerene-onion system, C 60@C 240, strong plasmonic couplings between the nested fullerenes are demonstrated. The resulting hybridization produces four cross-over plasmons generated from the bonding and antibonding mixing of excited charge clouds of individual fullerenes. This suggests the possibility of designing buckyonions exhibiting plasmon resonances with specified properties and may motivate future research to modify the resonances with encaged atoms, molecules or clusters.
|Journal||Journal of Physics B: Atomic, Molecular and Optical Physics|
|Publication status||Published - 28 Dec 2011|
ASJC Scopus subject areas
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics