Pilot-scale study on the treatment of basal aquifer water using ultrafiltration, reverse osmosis and evaporation/crystallization to achieve zero-liquid discharge

Kavithaa Loganathan, Pamela Chelme-Ayala, Mohamed Gamal El-Din

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Basal aquifer water is deep groundwater found at the bottom of geological formations, underlying bitumen-saturated sands. Some of the concerns associated with basal aquifer water at the Athabasca oil sands are the high concentrations of hardness-causing compounds, alkalinity, and total dissolved solids. The objective of this pilot-scale study was to treat basal aquifer water to a quality suitable for its reuse in the production of synthetic oil. To achieve zero-liquid discharge (ZLD) conditions, the treatment train included chemical oxidation, polymeric ultrafiltration (UF), reverse osmosis (RO), and evaporation-crystallization technologies. The results indicated that the UF unit was effective in removing solids, with UF filtrate turbidity averaging 2.0 NTU and silt density index averaging 0.9. Membrane autopsies indicated that iron was the primary foulant on the UF and RO membranes. Laboratory and pilot-scale tests on RO reject were conducted to determine the feasibility of ZLD crystallization. Due to the high amounts of calcium, magnesium, and bicarbonate in the RO reject, softening of the feed was required to avoid scaling in the evaporator. Crystals produced throughout the testing were mainly sodium chloride. The results of this study indicated that the ZLD approach was effective in both producing freshwater and minimizing brine discharges.

Original languageEnglish
Pages (from-to)213-223
Number of pages11
JournalJournal of Environmental Management
Volume165
DOIs
Publication statusPublished - 1 Jan 2016
Externally publishedYes

Fingerprint

Reverse osmosis
Ultrafiltration
ultrafiltration
Aquifers
Discharge (fluid mechanics)
Evaporation
crystallization
evaporation
Crystallization
aquifer
liquid
Liquids
Water
membrane
Osmosis membranes
water
Oil sands
Silt
oil sand
bitumen

Keywords

  • Basal aquifer water
  • Crystallization
  • Reverse osmosis
  • Ultrafiltration
  • Zero-liquid discharge

ASJC Scopus subject areas

  • Environmental Engineering
  • Waste Management and Disposal
  • Management, Monitoring, Policy and Law

Cite this

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title = "Pilot-scale study on the treatment of basal aquifer water using ultrafiltration, reverse osmosis and evaporation/crystallization to achieve zero-liquid discharge",
abstract = "Basal aquifer water is deep groundwater found at the bottom of geological formations, underlying bitumen-saturated sands. Some of the concerns associated with basal aquifer water at the Athabasca oil sands are the high concentrations of hardness-causing compounds, alkalinity, and total dissolved solids. The objective of this pilot-scale study was to treat basal aquifer water to a quality suitable for its reuse in the production of synthetic oil. To achieve zero-liquid discharge (ZLD) conditions, the treatment train included chemical oxidation, polymeric ultrafiltration (UF), reverse osmosis (RO), and evaporation-crystallization technologies. The results indicated that the UF unit was effective in removing solids, with UF filtrate turbidity averaging 2.0 NTU and silt density index averaging 0.9. Membrane autopsies indicated that iron was the primary foulant on the UF and RO membranes. Laboratory and pilot-scale tests on RO reject were conducted to determine the feasibility of ZLD crystallization. Due to the high amounts of calcium, magnesium, and bicarbonate in the RO reject, softening of the feed was required to avoid scaling in the evaporator. Crystals produced throughout the testing were mainly sodium chloride. The results of this study indicated that the ZLD approach was effective in both producing freshwater and minimizing brine discharges.",
keywords = "Basal aquifer water, Crystallization, Reverse osmosis, Ultrafiltration, Zero-liquid discharge",
author = "Kavithaa Loganathan and Pamela Chelme-Ayala and {Gamal El-Din}, Mohamed",
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AU - Chelme-Ayala, Pamela

AU - Gamal El-Din, Mohamed

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N2 - Basal aquifer water is deep groundwater found at the bottom of geological formations, underlying bitumen-saturated sands. Some of the concerns associated with basal aquifer water at the Athabasca oil sands are the high concentrations of hardness-causing compounds, alkalinity, and total dissolved solids. The objective of this pilot-scale study was to treat basal aquifer water to a quality suitable for its reuse in the production of synthetic oil. To achieve zero-liquid discharge (ZLD) conditions, the treatment train included chemical oxidation, polymeric ultrafiltration (UF), reverse osmosis (RO), and evaporation-crystallization technologies. The results indicated that the UF unit was effective in removing solids, with UF filtrate turbidity averaging 2.0 NTU and silt density index averaging 0.9. Membrane autopsies indicated that iron was the primary foulant on the UF and RO membranes. Laboratory and pilot-scale tests on RO reject were conducted to determine the feasibility of ZLD crystallization. Due to the high amounts of calcium, magnesium, and bicarbonate in the RO reject, softening of the feed was required to avoid scaling in the evaporator. Crystals produced throughout the testing were mainly sodium chloride. The results of this study indicated that the ZLD approach was effective in both producing freshwater and minimizing brine discharges.

AB - Basal aquifer water is deep groundwater found at the bottom of geological formations, underlying bitumen-saturated sands. Some of the concerns associated with basal aquifer water at the Athabasca oil sands are the high concentrations of hardness-causing compounds, alkalinity, and total dissolved solids. The objective of this pilot-scale study was to treat basal aquifer water to a quality suitable for its reuse in the production of synthetic oil. To achieve zero-liquid discharge (ZLD) conditions, the treatment train included chemical oxidation, polymeric ultrafiltration (UF), reverse osmosis (RO), and evaporation-crystallization technologies. The results indicated that the UF unit was effective in removing solids, with UF filtrate turbidity averaging 2.0 NTU and silt density index averaging 0.9. Membrane autopsies indicated that iron was the primary foulant on the UF and RO membranes. Laboratory and pilot-scale tests on RO reject were conducted to determine the feasibility of ZLD crystallization. Due to the high amounts of calcium, magnesium, and bicarbonate in the RO reject, softening of the feed was required to avoid scaling in the evaporator. Crystals produced throughout the testing were mainly sodium chloride. The results of this study indicated that the ZLD approach was effective in both producing freshwater and minimizing brine discharges.

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