Photoelectrochemical hydrogen production using CdS nanoparticles photodeposited onto Li-ion-inserted titania nanotube arrays

Unseock Kang, Kyu Jun Park, Dong Suk Han, Young Min Kim, Seungdo Kim, Hyunwoong Park

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

This study reports the synthesis of cadmium sulfide (CdS) nanoparticles on Li+-inserted TiO2 nanotube array (Li-TNA) to fabricate Li-TNA/CdS heterojunction electrodes for photoelectrochemical (PEC) hydrogen production under air mass (AM) 1.5 light and solar visible light (λ > 420 nm). For fabrication of the heterojunction, Li+ is rapidly inserted into TNA pre-grown on Ti foil, and CdS is then photodeposited onto the Li-TNA electrodes for varying deposition times. Surface analyses reveal that sub-100-nm polycrystalline CdS particles partly cover the Li-TNA (length: ∼800 nm, pore diameter: ∼100 nm), enabling the heterojunction to utilize AM 1.5 light as well as visible light. In aqueous solutions of sulfide and sulfite, the Li-TNA/CdS exhibits an incident photon-to-current efficiency (IPCE) of ∼20% (λ = 420 nm) while generating H2 at a Faradaic efficiency of ∼100%. This PEC performance is superior to that of TNA/CdS, which is attributed to the Li+-enhanced charge transfer at the TNA/CdS interface. Electrochemical impedance analysis shows that the charge-transfer resistance of the TNA is reduced by ∼60% by Li+ insertion. Time-resolved photoluminescence decay profiles further reveal that the charge transfer in Li-TNA is completed within 0.8 ns, which is ∼33% faster than that in TNA. The sample surface is analyzed using scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and ultraviolet–visible spectroscopy, and the PEC behavior of the samples is discussed in detail.

Original languageEnglish
Pages (from-to)289-295
Number of pages7
JournalCatalysis Today
Volume303
DOIs
Publication statusPublished - 1 Apr 2018

Fingerprint

Cadmium sulfide
Hydrogen production
Nanotubes
Titanium
Ions
Nanoparticles
Heterojunctions
Charge transfer
Sulfites
Electrodes
Sulfides
Air
cadmium sulfide
titanium dioxide
Metal foil
Photoluminescence
Photons
X ray photoelectron spectroscopy
Spectroscopy
Fabrication

Keywords

  • Artificial photosynthesis
  • CdS
  • Heterojunction
  • Solar fuel
  • TiO nanotubes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Photoelectrochemical hydrogen production using CdS nanoparticles photodeposited onto Li-ion-inserted titania nanotube arrays. / Kang, Unseock; Park, Kyu Jun; Han, Dong Suk; Kim, Young Min; Kim, Seungdo; Park, Hyunwoong.

In: Catalysis Today, Vol. 303, 01.04.2018, p. 289-295.

Research output: Contribution to journalArticle

Kang, Unseock ; Park, Kyu Jun ; Han, Dong Suk ; Kim, Young Min ; Kim, Seungdo ; Park, Hyunwoong. / Photoelectrochemical hydrogen production using CdS nanoparticles photodeposited onto Li-ion-inserted titania nanotube arrays. In: Catalysis Today. 2018 ; Vol. 303. pp. 289-295.
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abstract = "This study reports the synthesis of cadmium sulfide (CdS) nanoparticles on Li+-inserted TiO2 nanotube array (Li-TNA) to fabricate Li-TNA/CdS heterojunction electrodes for photoelectrochemical (PEC) hydrogen production under air mass (AM) 1.5 light and solar visible light (λ > 420 nm). For fabrication of the heterojunction, Li+ is rapidly inserted into TNA pre-grown on Ti foil, and CdS is then photodeposited onto the Li-TNA electrodes for varying deposition times. Surface analyses reveal that sub-100-nm polycrystalline CdS particles partly cover the Li-TNA (length: ∼800 nm, pore diameter: ∼100 nm), enabling the heterojunction to utilize AM 1.5 light as well as visible light. In aqueous solutions of sulfide and sulfite, the Li-TNA/CdS exhibits an incident photon-to-current efficiency (IPCE) of ∼20{\%} (λ = 420 nm) while generating H2 at a Faradaic efficiency of ∼100{\%}. This PEC performance is superior to that of TNA/CdS, which is attributed to the Li+-enhanced charge transfer at the TNA/CdS interface. Electrochemical impedance analysis shows that the charge-transfer resistance of the TNA is reduced by ∼60{\%} by Li+ insertion. Time-resolved photoluminescence decay profiles further reveal that the charge transfer in Li-TNA is completed within 0.8 ns, which is ∼33{\%} faster than that in TNA. The sample surface is analyzed using scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and ultraviolet–visible spectroscopy, and the PEC behavior of the samples is discussed in detail.",
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