Photocatalytic H2 production on trititanate nanotubes coupled with CdS and platinum nanoparticles under visible light: Revisiting H2 production and material durability

Hyunwoong Park, Hsin Hung Ou, Minju Kim, Unseock Kang, Dong Suk Han, Michael R. Hoffmann

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The photocatalytic production of molecular hydrogen (H2) on ternary composites of Pt, CdS, and sodium trititanate nanotubes (NaxH2-xTi3O7, TNTs) is examined in an aqueous 2-propanol (IPA) solution (typically 5 vol%) at a circum-neutral pH under visible light (λ > 420 nm). The H2 production rates are dependent on the Pt-loading level, and the optimum production rate in the Pt/CdS/TNTs is approximately six times higher than that in Pt/CdS/TiO2. A D2O solution containing 5 vol% IPA leads only to the production of D2 molecules, whereas increasing the IPA amount to 30 vol% leads to the production of DH molecules. This indicates that the Pt/CdS/TNTs composites enable H2 production via true water splitting under our typical experimental conditions. X-ray photoelectron spectroscopy (XPS) analyses of the as-synthesized Pt/CdS/TNTs and those used for 6 and 12 h show that metallic Pt on the CdS/TNTs is less susceptible to oxidation than Pt on CdS/TiO2. In addition, photocorrosion of CdS (i.e., sulfate formation) is significantly inhibited during the photocatalytic H2 production reactions in the Pt/CdS/TNTs because of the efficient charge transfer via the TNTs framework. The Pt/CdS/TNTs samples are thermally more stable than Pt/CdS/TiO2 and CdS/TNTs, effectively inhibiting the formation of CdO during the thermal synthesis. Detailed surface characterizations of the as-synthesized ternary composites are performed using X-ray diffraction, transmission electron microscopy, energy dispersive spectroscopy, and XPS.

Original languageEnglish
Pages (from-to)419-431
Number of pages13
JournalFaraday Discussions
Volume198
DOIs
Publication statusPublished - 1 Jan 2017

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Trinitrotoluene
trinitrotoluene
Platinum
durability
Nanotubes
nanotubes
Durability
platinum
Nanoparticles
nanoparticles
composite materials
Composite materials
X ray photoelectron spectroscopy
photoelectron spectroscopy
Molecules
water splitting
x rays
2-Propanol
Sulfates
Charge transfer

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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Photocatalytic H2 production on trititanate nanotubes coupled with CdS and platinum nanoparticles under visible light : Revisiting H2 production and material durability. / Park, Hyunwoong; Ou, Hsin Hung; Kim, Minju; Kang, Unseock; Han, Dong Suk; Hoffmann, Michael R.

In: Faraday Discussions, Vol. 198, 01.01.2017, p. 419-431.

Research output: Contribution to journalArticle

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abstract = "The photocatalytic production of molecular hydrogen (H2) on ternary composites of Pt, CdS, and sodium trititanate nanotubes (NaxH2-xTi3O7, TNTs) is examined in an aqueous 2-propanol (IPA) solution (typically 5 vol{\%}) at a circum-neutral pH under visible light (λ > 420 nm). The H2 production rates are dependent on the Pt-loading level, and the optimum production rate in the Pt/CdS/TNTs is approximately six times higher than that in Pt/CdS/TiO2. A D2O solution containing 5 vol{\%} IPA leads only to the production of D2 molecules, whereas increasing the IPA amount to 30 vol{\%} leads to the production of DH molecules. This indicates that the Pt/CdS/TNTs composites enable H2 production via true water splitting under our typical experimental conditions. X-ray photoelectron spectroscopy (XPS) analyses of the as-synthesized Pt/CdS/TNTs and those used for 6 and 12 h show that metallic Pt on the CdS/TNTs is less susceptible to oxidation than Pt on CdS/TiO2. In addition, photocorrosion of CdS (i.e., sulfate formation) is significantly inhibited during the photocatalytic H2 production reactions in the Pt/CdS/TNTs because of the efficient charge transfer via the TNTs framework. The Pt/CdS/TNTs samples are thermally more stable than Pt/CdS/TiO2 and CdS/TNTs, effectively inhibiting the formation of CdO during the thermal synthesis. Detailed surface characterizations of the as-synthesized ternary composites are performed using X-ray diffraction, transmission electron microscopy, energy dispersive spectroscopy, and XPS.",
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