Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells

Kurtis P. Recknagle, Emily M. Ryan, Moe A. Khaleel

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

A c ell-level distributed electrochemistry (DEC) modeling tool has been developed to enable predicting trends in solid oxide fuel cell performance by considering the coupled and spatially varying multi-physics that occur within the tri-layer. The approach calculates the distributed electrochemistry within the electrodes, which includes the charge transfer and electric potential fields, ion transport throughout the tri-layer, and gas distributions within the composite and porous electrodes. The thickness of the electrochemically active regions within the electrodes is calculated along with the distributions of charge transfer. The DEC modeling tool can examine the overall SOFC performance based on electrode microstructural parameters, such as particle size, pore size, porosity, electrolyte-and electrode-phase volume fractions, and triple-phase-boundary length. Recent developments in electrode fabrication methods have lead to increased interest in using graded and nano-structured electrodes to improve the electrochemical performance of SOFCs. This paper demonstrates how the DEC modeling tool can be used to help design novel electrode microstructures by optimizing a graded anode for high electrochemical performance.

Original languageEnglish
Title of host publicationASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011
Pages571-580
Number of pages10
Volume4
EditionPARTS A AND B
Publication statusPublished - 1 Dec 2011
Externally publishedYes
EventASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011 - Denver, CO, United States
Duration: 11 Nov 201117 Nov 2011

Other

OtherASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011
CountryUnited States
CityDenver, CO
Period11/11/1117/11/11

Fingerprint

Electrochemistry
Solid oxide fuel cells (SOFC)
Electrodes
Charge transfer
Phase boundaries
Pore size
Volume fraction
Anodes
Physics
Porosity
Particle size
Electrolytes
Fabrication
Microstructure
Composite materials
Ions
Electric potential
Gases

ASJC Scopus subject areas

  • Mechanical Engineering

Cite this

Recknagle, K. P., Ryan, E. M., & Khaleel, M. A. (2011). Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells. In ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011 (PARTS A AND B ed., Vol. 4, pp. 571-580)

Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells. / Recknagle, Kurtis P.; Ryan, Emily M.; Khaleel, Moe A.

ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011. Vol. 4 PARTS A AND B. ed. 2011. p. 571-580.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Recknagle, KP, Ryan, EM & Khaleel, MA 2011, Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells. in ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011. PARTS A AND B edn, vol. 4, pp. 571-580, ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011, Denver, CO, United States, 11/11/11.
Recknagle KP, Ryan EM, Khaleel MA. Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells. In ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011. PARTS A AND B ed. Vol. 4. 2011. p. 571-580
Recknagle, Kurtis P. ; Ryan, Emily M. ; Khaleel, Moe A. / Numerical modeling of the distributed electrochemistry and performance of solid oxide fuels cells. ASME 2011 International Mechanical Engineering Congress and Exposition, IMECE 2011. Vol. 4 PARTS A AND B. ed. 2011. pp. 571-580
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