Mutual Solubilities of Hydrocarbons and Water

III. 1-Hexene, 1-Octene, C10-C12 Hydrocarbons

Ioannis Economou, J. L. Heidman, C. Tsonopoulos, G. M. Wilson

Research output: Contribution to journalArticle

93 Citations (Scopus)

Abstract

This article completes the analysis of high-temperature mutual solubilities of hydrocarbons and water. Part I (Tsonopoulos and Wilson, 1983) presented benzene, cyclohexane, and n-hexane, while Part II (Heidman et al., 1985) extended the investigation to ethylbenzene, ethylcyclohexane, and n-octane. Part III presents experimental data up to the three-phase critical end point for C6, C8, and C10 1-alkenes, n-decane, n-butylcyclohexane, m-diethylbenzene, p-diisopropylbenzene, cis-decalin, tetralin, 1-methylnaphthalene, and 1-ethylnaphthalene. The thermodynamic analysis of Henry's constants for hydrocarbons in water is extended to the critical temperature of water, while the solubility and volatility of water in hydrocarbons are successfully correlated with several modifications of the Redlich-Kwong equation of state.

Original languageEnglish
Pages (from-to)535-546
Number of pages12
JournalAICHE Journal
Volume43
Issue number2
Publication statusPublished - Feb 1997
Externally publishedYes

Fingerprint

Hydrocarbons
Solubility
diisopropylbenzene
Water
Volatilization
Temperature
Ethylbenzene
Alkenes
Cyclohexane
Benzene
Hexane
Thermodynamics
Equations of state
Olefins
1-octene
1-hexene

ASJC Scopus subject areas

  • Biotechnology
  • Chemical Engineering(all)
  • Mechanical Engineering
  • Environmental Engineering
  • Polymers and Plastics

Cite this

Economou, I., Heidman, J. L., Tsonopoulos, C., & Wilson, G. M. (1997). Mutual Solubilities of Hydrocarbons and Water: III. 1-Hexene, 1-Octene, C10-C12 Hydrocarbons. AICHE Journal, 43(2), 535-546.

Mutual Solubilities of Hydrocarbons and Water : III. 1-Hexene, 1-Octene, C10-C12 Hydrocarbons. / Economou, Ioannis; Heidman, J. L.; Tsonopoulos, C.; Wilson, G. M.

In: AICHE Journal, Vol. 43, No. 2, 02.1997, p. 535-546.

Research output: Contribution to journalArticle

Economou, I, Heidman, JL, Tsonopoulos, C & Wilson, GM 1997, 'Mutual Solubilities of Hydrocarbons and Water: III. 1-Hexene, 1-Octene, C10-C12 Hydrocarbons', AICHE Journal, vol. 43, no. 2, pp. 535-546.
Economou, Ioannis ; Heidman, J. L. ; Tsonopoulos, C. ; Wilson, G. M. / Mutual Solubilities of Hydrocarbons and Water : III. 1-Hexene, 1-Octene, C10-C12 Hydrocarbons. In: AICHE Journal. 1997 ; Vol. 43, No. 2. pp. 535-546.
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