Microwave assisted glycolysis of poly(ethylene terephthalate) catalyzed by 1-butyl-3-methylimidazolium bromide ionic liquid

Mohamed A. Alnaqbi, Mahmoud A. Mohsin, Reneesh M. Busheer, Yousef Haik

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The combination of ionic liquid (IL) associated with microwave energy may have some potential application in the chemical recycling of poly (ethylene terephthalate). In this processes, glycolysis of waste poly (ethylene terephthalate) recovered from bottled water containers were thermally depolymerized with solvent ethylene glycol (EG) in the presence of 1-butyl-3-methyl imidazolium bromide ([bmim]Br) as catalyst (IL) under microwave condition. It was found that the glycolysis products consist of bis (2-hydroxyethyl) terephthalate (BHET) monomer that separated from the catalyst IL in pure crystalline form. The conversion of PET reach up to 100% and the yield of BHET reached 64% (wt %). The optimum performance was achieved by the use of 1-butyl-3-methyl imidazolium bromide as a catalyst, microwave irradiations temperature (170-175°C) and reaction time 1.75-2 h. The main glycolysis products were analyzed by 1H NMR, 13C NMR, LC-MS, FTIR, DSC, and TGA. When compared to conventional heating methods, microwave irradiation during glycolysis of PET resulted in short reaction time and more control over the temperature. This has allowed substantial saving in energy and processing cost. In addition, a more efficient, environmental-friendly, and economically feasible chemical recycling of waste PET was achieved in a significantly reduced reaction time.

Original languageEnglish
Article number41666
JournalJournal of Applied Polymer Science
Volume132
Issue number12
DOIs
Publication statusPublished - 1 Mar 2015
Externally publishedYes

Fingerprint

Ionic Liquids
Polyethylene Terephthalates
Ionic liquids
Polyethylene terephthalates
Microwaves
Microwave irradiation
Bromides
Catalysts
Recycling
Nuclear magnetic resonance
Ethylene Glycol
Ethylene glycol
Drinking Water
Containers
Monomers
Crystalline materials
Heating
Temperature
1-butyl-3-methylimidazolium chloride
Glycolysis

Keywords

  • degradation
  • glass transition
  • ionic liquids
  • properties and characterization
  • recycling

ASJC Scopus subject areas

  • Materials Chemistry
  • Polymers and Plastics
  • Surfaces, Coatings and Films
  • Chemistry(all)

Cite this

Microwave assisted glycolysis of poly(ethylene terephthalate) catalyzed by 1-butyl-3-methylimidazolium bromide ionic liquid. / Alnaqbi, Mohamed A.; Mohsin, Mahmoud A.; Busheer, Reneesh M.; Haik, Yousef.

In: Journal of Applied Polymer Science, Vol. 132, No. 12, 41666, 01.03.2015.

Research output: Contribution to journalArticle

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