Investigation of the physicochemical characteristics of ancient mortars by static and dynamic studies

Nikolaos M. Zouridakis, Ioannis Economou, Konstantinos P. Tzevelekos, Efstathios S. Kikkinides

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The present work focuses on the investigation of physicochemical characteristics of ancient mortars through the use of static and dynamic methods. Pore structure characteristics of limestone mortars are determined by means of the mercury porosimetry technique. Preliminary results show an average pore size of <900 angstroms, indicating the major role of macropores in the mortars. A pseudo-first order reaction-diffusion model is developed for investigating the transport and reaction of CO2 on such samples. The model is solved for each isotope of CO2 and the isotopic fractionation is determined as a function of distance from the surface of the mortar. The model's results are fitted to experimental data on carbon isotopic compositions obtained on these mortars. From the optimum fitted parameters, it follows that pore diffusion has a significant effect on the reaction rate of CO2 on the structure of the ancient mortars.

Original languageEnglish
Pages (from-to)1151-1155
Number of pages5
JournalCement and Concrete Research
Volume30
Issue number7
DOIs
Publication statusPublished - 2000
Externally publishedYes

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Mortar
Calcium Carbonate
Fractionation
Pore structure
Limestone
Mercury
Isotopes
Pore size
Reaction rates
Carbon
Chemical analysis

ASJC Scopus subject areas

  • Building and Construction
  • Materials Science(all)

Cite this

Investigation of the physicochemical characteristics of ancient mortars by static and dynamic studies. / Zouridakis, Nikolaos M.; Economou, Ioannis; Tzevelekos, Konstantinos P.; Kikkinides, Efstathios S.

In: Cement and Concrete Research, Vol. 30, No. 7, 2000, p. 1151-1155.

Research output: Contribution to journalArticle

Zouridakis, Nikolaos M. ; Economou, Ioannis ; Tzevelekos, Konstantinos P. ; Kikkinides, Efstathios S. / Investigation of the physicochemical characteristics of ancient mortars by static and dynamic studies. In: Cement and Concrete Research. 2000 ; Vol. 30, No. 7. pp. 1151-1155.
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