Influence of fuel ratio on the performance of combustion synthesized bifunctional cobalt oxide catalysts for fuel cell application

Anchu Ashok, Anand Kumar, Rahul R. Bhosale, Fares Almomani, Mohd Ali H. Saleh Saad, Sergey Suslov, Faris Tarlochan

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Solution combustion synthesis was used to prepare cobalt oxide nanoparticles at different fuel ratio (ϕ = 0.5, 1, and 1.75). The synthesized particles were characterized using XRD, SEM, TEM, FTIR and XPS to study the morphological and structural features. The fuel rich condition provides a reducing atmosphere limiting further oxidation of synthesized nanoparticles but produces more carbon residue on the catalyst surface compared to fuel lean conditions. Increasing the fuel ratio (ϕ value) from 0.5 to 1.75 increases the crystallite size and lowers the surface area. The electrocatalytic performance studies conducted by cyclic voltammetry (CV) and linear sweep voltammetry (LSV) indicate significant changes in catalytic activities due to variation in synthesis conditions. The LSV results obtained between potential of -1.2 V and 0.75 V shows all the three cobalt oxide catalysts to have bifunctional properties of being active for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), with Co synthesized at lower fuel ratio (ϕ = 0.5) displaying the highest current density. The onset potential for Co (ϕ = 0.5) is more positive than Co (ϕ = 1) and Co (ϕ = 1.75). The kinetic current density for Co (ϕ = 0.5) is 6.45 mA cm-2 and decreases with increase in fuel ratio. The OER current starts at 0.45 V for all the catalysts showing maximum density for Co (ϕ = 0.5) and gradually decreasing for catalysts synthesized at higher fuel ratio.

Original languageEnglish
JournalInternational Journal of Hydrogen Energy
DOIs
Publication statusAccepted/In press - 1 Jan 2018

Fingerprint

cobalt oxides
fuel cells
Fuel cells
Cobalt
catalysts
Catalysts
Oxides
Voltammetry
Oxygen
oxygen
Current density
current density
Nanoparticles
combustion synthesis
nanoparticles
Combustion synthesis
Crystallite size
Cyclic voltammetry
high current
catalytic activity

Keywords

  • Cobalt oxide catalyst
  • Electrocatalysis
  • Fuel cell
  • Oxygen evolution reaction
  • Oxygen reduction reaction
  • Solution combustion synthesis

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Influence of fuel ratio on the performance of combustion synthesized bifunctional cobalt oxide catalysts for fuel cell application. / Ashok, Anchu; Kumar, Anand; Bhosale, Rahul R.; Almomani, Fares; Saleh Saad, Mohd Ali H.; Suslov, Sergey; Tarlochan, Faris.

In: International Journal of Hydrogen Energy, 01.01.2018.

Research output: Contribution to journalArticle

Ashok, Anchu ; Kumar, Anand ; Bhosale, Rahul R. ; Almomani, Fares ; Saleh Saad, Mohd Ali H. ; Suslov, Sergey ; Tarlochan, Faris. / Influence of fuel ratio on the performance of combustion synthesized bifunctional cobalt oxide catalysts for fuel cell application. In: International Journal of Hydrogen Energy. 2018.
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AU - Saleh Saad, Mohd Ali H.

AU - Suslov, Sergey

AU - Tarlochan, Faris

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AB - Solution combustion synthesis was used to prepare cobalt oxide nanoparticles at different fuel ratio (ϕ = 0.5, 1, and 1.75). The synthesized particles were characterized using XRD, SEM, TEM, FTIR and XPS to study the morphological and structural features. The fuel rich condition provides a reducing atmosphere limiting further oxidation of synthesized nanoparticles but produces more carbon residue on the catalyst surface compared to fuel lean conditions. Increasing the fuel ratio (ϕ value) from 0.5 to 1.75 increases the crystallite size and lowers the surface area. The electrocatalytic performance studies conducted by cyclic voltammetry (CV) and linear sweep voltammetry (LSV) indicate significant changes in catalytic activities due to variation in synthesis conditions. The LSV results obtained between potential of -1.2 V and 0.75 V shows all the three cobalt oxide catalysts to have bifunctional properties of being active for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), with Co synthesized at lower fuel ratio (ϕ = 0.5) displaying the highest current density. The onset potential for Co (ϕ = 0.5) is more positive than Co (ϕ = 1) and Co (ϕ = 1.75). The kinetic current density for Co (ϕ = 0.5) is 6.45 mA cm-2 and decreases with increase in fuel ratio. The OER current starts at 0.45 V for all the catalysts showing maximum density for Co (ϕ = 0.5) and gradually decreasing for catalysts synthesized at higher fuel ratio.

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