Influence of bias voltage on the structure and deposition mechanism of diamond-like carbon films produced by RF (13.56 MHz) CH4 plasma

M. Ouchabane, H. Salah, M. Herrmann, Nouar Tabet, K. Henda, B. Touchrift, M. Kechouane

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Plasma enhanced chemical vapour deposition technique (PECVD) was used to grow diamond-like carbon films using pure methane gas plasma. Structural, optical and mechanical properties of the obtained a-C:H films were investigated as a function of bias voltage in the range 120-270 V, using different techniques. Elastic recoil detection analysis (ERDA) was employed to determine the hydrogen content and Fourier transform infrared spectroscopy (FTIR) was used to analyse the absorption of optically active hydrogen in the deposited films. The relative concentrations of sp 2 and sp 3 groups were determined from fitting of both X-ray photoelectron spectroscopy (XPS) and FTIR spectra. Mechanical hardness and optical transmission were determined using nanoindentation and spectrophotometry, respectively. The results showed that the structure and properties of the films formed strongly depended on the applied bias voltage. In the range of energy considered the growth of the films was governed by a competition between both chemical and physical processes, with a dominance of physical process (subplantation) above 240 V, the energy at which more than 90% sp 3 hybridization was obtained. Nanoindentation tests revealed hardness and Young's modulus of the films ranging from 12-15 and 116-155 GP a, respectively. The optical gap values deduced from the optical transmission spectra varied between 1.13 and 1.60 eV.

Original languageEnglish
Pages (from-to)2311-2318
Number of pages8
JournalPhysica Status Solidi (A) Applications and Materials Science
Volume207
Issue number10
DOIs
Publication statusPublished - 1 Oct 2010
Externally publishedYes

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Keywords

  • Amorphous semiconductors
  • Chemical vapour deposition
  • Diamond-like carbon
  • Infrared spectra
  • Mechanical properties
  • Optical properties

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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