Hydrogen Bonding and Stability of Hybrid Organic–Inorganic Perovskites

Fadwa El-Mellouhi, Asma Marzouk, El Tayeb Bentria, Sergey Rashkeev, Sabre Kais, Fahhad Alharbi

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

In the past few years, the efficiency of solar cells based on hybrid organic–inorganic perovskites has exceeded the level needed for commercialization. However, existing perovskites solar cells (PSCs) suffer from several intrinsic instabilities, which prevent them from reaching industrial maturity, and stabilizing PSCs has become a critically important problem. Here we propose to stabilize PSCs chemically by strengthening the interactions between the organic cation and inorganic anion of the perovskite framework. In particular, we show that replacing the methylammonium cation with alternative protonated cations allows an increase in the stability of the perovskite by forming strong hydrogen bonds with the halide anions. This interaction also provides opportunities for tuning the electronic states near the bandgap. These mechanisms should have a universal character in different hybrid organic–inorganic framework materials that are widely used.

Original languageEnglish
Pages (from-to)2648-2655
Number of pages8
JournalChemSusChem
Volume9
Issue number18
DOIs
Publication statusPublished - 22 Sep 2016

Fingerprint

Solar cells
Hydrogen bonds
hydrogen
Cations
cation
Positive ions
perovskite
Perovskite
Anions
anion
Negative ions
halide
commercialization
Electronic states
Energy gap
Tuning
solar cell

Keywords

  • density functional theory
  • hydrogen bonding
  • perovskite
  • solar cells
  • stability

ASJC Scopus subject areas

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)

Cite this

Hydrogen Bonding and Stability of Hybrid Organic–Inorganic Perovskites. / El-Mellouhi, Fadwa; Marzouk, Asma; Bentria, El Tayeb; Rashkeev, Sergey; Kais, Sabre; Alharbi, Fahhad.

In: ChemSusChem, Vol. 9, No. 18, 22.09.2016, p. 2648-2655.

Research output: Contribution to journalArticle

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