High-performance thin-film-transistors based on semiconducting-enriched single-walled carbon nanotubes processed by electrical-breakdown strategy

Brahim Aissa, M. Nedil, M. A. Habib, E. H. Abdul-Hafidh, F. Rosei

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Over the past two decades, among remarkable variety of nanomaterials, single-walled carbon nanotubes (SWCNTs) remain the most intriguing and uniquely well suited materials for applications in high-performance electronics. The most advanced technologies require the ability to form purely semiconducting SWCNTs. Here, we report on our strategy based on the well known progressive electrical breakdown process that offer this capability and serves as highly efficient means for selectively removing metallic carbon nanotubes from electronically heterogeneous random networks, deposited on silicon substrates in a thin film transistor (TFT) configuration. We demonstrate the successful achievement of semiconducting enriched-SWCNT networks in TFT scheme that reach On/Off switching ratios of ∼100,000, on-conductance of 20 μS, and a subthreshold swing of less than 165 mV/decades. The obtained TFT devices were then protected with thin film poly(methyl methacrylate) (PMMA) to keep the percolation level of the SWCNTs network spatially and temporally stable, while protecting it from atmosphere exchanges. TFT devices were found to be air-stable and maintained their excellent characteristics in ambient atmosphere for more than 4 months. This approach could work as a platform for future nanotube-based nanoelectronics.

Original languageEnglish
Pages (from-to)349-355
Number of pages7
JournalApplied Surface Science
Volume328
DOIs
Publication statusPublished - 15 Feb 2015

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Keywords

  • Carbon nanotubes
  • Electrical-breackdown
  • On/Off switching ratio
  • Thin-film-transistor

ASJC Scopus subject areas

  • Surfaces, Coatings and Films

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