Abstract
Nitrogen functionalities such as pyridinic-nitrogen, pyrrolic-nitrogen and graphitic-nitrogen based active sites are commonly produced when nitrogen precursors are pyrolyzed on carbon matrix. In this study, we demonstrate two catalysts prepared via pyrolysis of Polyaniline and Vinazene with carbon. Their excellent Oxygen reduction reaction (ORR) activities and potential cycling stability were confirmed using thin film rotating ring-disk electrode (RRDE) in 0.1 M KOH and 0.1 M HClO4. Structural-performance correlation analysis confirms that not only graphitic nitrogen is responsible for high ORR, but also other nitrogen functions including pyrrolic one. However, catalyst that is rich in graphitic-N shows more stability especially in acidic medium.
| Original language | English |
|---|---|
| Title of host publication | Materials Today: Proceedings |
| Publisher | Elsevier Ltd |
| Pages | 691-695 |
| Number of pages | 5 |
| Volume | 3 |
| Edition | 2 |
| DOIs | |
| Publication status | Published - 2016 |
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Keywords
- Electrocatalysts
- Fuel Cells
- Nitrogen doped carbon
- Oxygen reduction reaction
- Polyaniline
- Vinazene
ASJC Scopus subject areas
- Materials Science(all)
Cite this
Further Understanding of Nitrogen-Doped Carbon Catalytic Property towards Oxygen Reduction Reaction (ORR). / Merzougui, Belabbes; Bukola, Saheed; Zaffou, Rachid.
Materials Today: Proceedings. Vol. 3 2. ed. Elsevier Ltd, 2016. p. 691-695.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Further Understanding of Nitrogen-Doped Carbon Catalytic Property towards Oxygen Reduction Reaction (ORR)
AU - Merzougui, Belabbes
AU - Bukola, Saheed
AU - Zaffou, Rachid
PY - 2016
Y1 - 2016
N2 - Nitrogen functionalities such as pyridinic-nitrogen, pyrrolic-nitrogen and graphitic-nitrogen based active sites are commonly produced when nitrogen precursors are pyrolyzed on carbon matrix. In this study, we demonstrate two catalysts prepared via pyrolysis of Polyaniline and Vinazene with carbon. Their excellent Oxygen reduction reaction (ORR) activities and potential cycling stability were confirmed using thin film rotating ring-disk electrode (RRDE) in 0.1 M KOH and 0.1 M HClO4. Structural-performance correlation analysis confirms that not only graphitic nitrogen is responsible for high ORR, but also other nitrogen functions including pyrrolic one. However, catalyst that is rich in graphitic-N shows more stability especially in acidic medium.
AB - Nitrogen functionalities such as pyridinic-nitrogen, pyrrolic-nitrogen and graphitic-nitrogen based active sites are commonly produced when nitrogen precursors are pyrolyzed on carbon matrix. In this study, we demonstrate two catalysts prepared via pyrolysis of Polyaniline and Vinazene with carbon. Their excellent Oxygen reduction reaction (ORR) activities and potential cycling stability were confirmed using thin film rotating ring-disk electrode (RRDE) in 0.1 M KOH and 0.1 M HClO4. Structural-performance correlation analysis confirms that not only graphitic nitrogen is responsible for high ORR, but also other nitrogen functions including pyrrolic one. However, catalyst that is rich in graphitic-N shows more stability especially in acidic medium.
KW - Electrocatalysts
KW - Fuel Cells
KW - Nitrogen doped carbon
KW - Oxygen reduction reaction
KW - Polyaniline
KW - Vinazene
UR - http://www.scopus.com/inward/record.url?scp=84963612523&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84963612523&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2016.01.113
DO - 10.1016/j.matpr.2016.01.113
M3 - Conference contribution
AN - SCOPUS:84963612523
VL - 3
SP - 691
EP - 695
BT - Materials Today: Proceedings
PB - Elsevier Ltd
ER -