Functionalization of the surface of ceramic membranes with 3-mercaptopropyl groups using the sol-gel method

V. V. Tomina, I. V. Mel'Nik, R. P. Pogorilyi, Viktor Kochkodan, Yu L. Zub

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Tubular ceramic membranes based on α-Al2O3 were functionalized with 3-mercaptopropyl groups using the sol-gel method. The formation of the polysiloxane layer on the inner surface of the membranes was confirmed by SEM images and FTIR spectroscopy data. The functionalized membranes (identically to the original one) retain the high performance typical of highly efficient microfiltration membranes (320-690 L/m2 h); however, they can be used to remove silver(I) ions from water due to the formation of complexes between thiol groups of the active layer and silver(I) ions. It was also shown that the decreasing concentration of functionalizing sol produces a thinner surface polysiloxane layer with more active sites available for the sorption of Ag+ ions. Thus, fourfold dilution of the starting sol results in a tenfold increase in the sorption of Ag+ ions calculated per mass unit of the functionalizing layer (from 23 to 203 mg/g).

Original languageEnglish
Pages (from-to)386-391
Number of pages6
JournalProtection of Metals and Physical Chemistry of Surfaces
Volume49
Issue number4
DOIs
Publication statusPublished - Jul 2013
Externally publishedYes

Fingerprint

Ceramic membranes
Sol-gel process
Ions
Siloxanes
Polymethyl Methacrylate
Sols
Membranes
Silver
Silicones
Sorption
Microfiltration
Sulfhydryl Compounds
Dilution
Spectroscopy
Scanning electron microscopy
Water

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Metals and Alloys
  • Surfaces, Coatings and Films

Cite this

Functionalization of the surface of ceramic membranes with 3-mercaptopropyl groups using the sol-gel method. / Tomina, V. V.; Mel'Nik, I. V.; Pogorilyi, R. P.; Kochkodan, Viktor; Zub, Yu L.

In: Protection of Metals and Physical Chemistry of Surfaces, Vol. 49, No. 4, 07.2013, p. 386-391.

Research output: Contribution to journalArticle

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AU - Zub, Yu L.

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