Fe3O4-Ag2WO4: Facile synthesis, characterization and visible light assisted photocatalytic activity

Satheesh Rajamohan, Vignesh Kumaravel, Rajarajan Muthuramalingam, Suganthi Ayyadurai, Ahmed Abdel-Wahab, Byeong Sub Kwak, Misook Kang, Srimala Sreekantan

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A Fe3O4-Ag2WO4 nano-composite was prepared through a sono-chemical route. Its physico-chemical properties were successfully characterized using XRD, BET, VSM, UV-vis-DRS, SEM, EDX, HR-TEM and PL techniques. The surface area of the Fe3O4-Ag2WO4 nano-composite was higher than those of pure Fe3O4 and Ag2WO4. The photocatalytic activity was tested for the degradation of a fast green (FG) dye under visible light irradiation. The Fe3O4-Ag2WO4 nano-composite showed good photocatalytic activity (81.11% of FG degradation within 120 min) when compared to Fe3O4, Ag2WO4, ZnO, and TiO2 (P25). The improved photocatalytic activity of the nano-composite was ascribed to efficient electron-hole separation. Fe3O4-Ag2WO4 was found to be a durable and stable photocatalyst during recycling experiments. A plausible mechanism for the electron-hole separation process on the heterojunction was also proposed.

Original languageEnglish
Pages (from-to)11722-11730
Number of pages9
JournalNew Journal of Chemistry
Volume41
Issue number20
DOIs
Publication statusPublished - 1 Jan 2017
Externally publishedYes

    Fingerprint

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

Cite this

Rajamohan, S., Kumaravel, V., Muthuramalingam, R., Ayyadurai, S., Abdel-Wahab, A., Sub Kwak, B., Kang, M., & Sreekantan, S. (2017). Fe3O4-Ag2WO4: Facile synthesis, characterization and visible light assisted photocatalytic activity. New Journal of Chemistry, 41(20), 11722-11730. https://doi.org/10.1039/c7nj03004e