Facile In Situ Fabrication of Nanostructured Graphene–CuO Hybrid with Hydrogen Sulfide Removal Capacity

Sunil P. Lonkar, Vishnu V. Pillai, Samuel Stephen, Ahmed Abdala, Vikas Mittal

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

A simple and scalable synthetic approach for one-step synthesis of graphene–CuO (TRGC) nanocomposite by an in situ thermo-annealing method has been developed. Using graphene oxide (GO) and copper hydroxide as a precursors reagent, the reduction of GO and the uniform deposition of in situ formed CuO nanoparticles on graphene was simultaneously achieved. The method employed no solvents, toxic-reducing agents, or organic modifiers. The resulting nanostructured hybrid exhibited improved H2S sorption capacity of 1.5 mmol H2S/g-sorbent (3 g S/100 g-sorbent). Due to its highly dispersed sub-20 nm CuO nanoparticles and large specific surface area, TRGC nanocomposite exhibits tremendous potential for energy and environment applications.

Original languageEnglish
Pages (from-to)312-319
Number of pages8
JournalNano-Micro Letters
Volume8
Issue number4
DOIs
Publication statusPublished - 1 Oct 2016
Externally publishedYes

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Graphene
Sorbents
Fabrication
Oxides
Nanocomposites
Nanoparticles
Poisons
Reducing Agents
Reducing agents
Specific surface area
Sorption
Annealing
Copper

Keywords

  • Adsorption
  • Breakthrough capacity
  • CuO/graphene
  • Hydrogen sulfide
  • In situ synthesis
  • Thermal stability

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films

Cite this

Facile In Situ Fabrication of Nanostructured Graphene–CuO Hybrid with Hydrogen Sulfide Removal Capacity. / Lonkar, Sunil P.; Pillai, Vishnu V.; Stephen, Samuel; Abdala, Ahmed; Mittal, Vikas.

In: Nano-Micro Letters, Vol. 8, No. 4, 01.10.2016, p. 312-319.

Research output: Contribution to journalArticle

Lonkar, Sunil P. ; Pillai, Vishnu V. ; Stephen, Samuel ; Abdala, Ahmed ; Mittal, Vikas. / Facile In Situ Fabrication of Nanostructured Graphene–CuO Hybrid with Hydrogen Sulfide Removal Capacity. In: Nano-Micro Letters. 2016 ; Vol. 8, No. 4. pp. 312-319.
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