Experimental study of the aging and self-healing of the glass/ceramic sealant used in SOFCs

Wenning N. Liu, Xin Sun, Brian Koeppel, Mohammad Khaleel

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

High operating temperatures of solid oxide fuel cells (SOFCs) require that the sealant must function at a high temperature between 600°C and 900°C and in the oxidizing and reducing environments of fuel and air. This paper describes tests to investigate the temporal evolution of the volume fraction of ceramic phases, the evolution of micro-damage, and the self-healing behavior of the glass-ceramic sealant used in SOFCs. It was found that after the initial sintering process, further crystallization of the glass-ceramic sealant does not stop, but slows down and reduces the residual glass content while boosting the ceramic crystalline content. Under a long-term operating environment, distinct fibrous and needle-like crystals in the amorphous phase disappeared, and smeared/diffused phase boundaries between the glass phase and ceramic phase were observed. Meanwhile, the micro-damage was induced by the cooling down process from the operating temperature to room temperature, which can potentially degrade the mechanical properties of the glass/ceramic sealant. The glass/ceramic sealant exhibited self-healing upon reheating to the SOFC operating temperature, which can restore the mechanical performance of the glass/ceramic sealant.

Original languageEnglish
Pages (from-to)22-29
Number of pages8
JournalInternational Journal of Applied Ceramic Technology
Volume7
Issue number1
DOIs
Publication statusPublished - 1 Jan 2010
Externally publishedYes

Fingerprint

sealers
Sealants
healing
Glass ceramics
solid oxide fuel cells
Solid oxide fuel cells (SOFC)
Aging of materials
ceramics
glass
operating temperature
Temperature
Glass
Phase boundaries
Crystallization
damage
Needles
Fuel cell
Experimental study
Healing
Volume fraction

ASJC Scopus subject areas

  • Ceramics and Composites
  • Marketing
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Experimental study of the aging and self-healing of the glass/ceramic sealant used in SOFCs. / Liu, Wenning N.; Sun, Xin; Koeppel, Brian; Khaleel, Mohammad.

In: International Journal of Applied Ceramic Technology, Vol. 7, No. 1, 01.01.2010, p. 22-29.

Research output: Contribution to journalArticle

Liu, Wenning N. ; Sun, Xin ; Koeppel, Brian ; Khaleel, Mohammad. / Experimental study of the aging and self-healing of the glass/ceramic sealant used in SOFCs. In: International Journal of Applied Ceramic Technology. 2010 ; Vol. 7, No. 1. pp. 22-29.
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