Experimental approaches to feed solution permeability in pressure-driven membrane separation processes

M. Toffoletto, A. A. Merdaw, A. O. Sharif, A. Bertucco

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

This study demonstrates the application of the solution-diffusion pore-flow fluid-resistance (SDPFFR) model, which is used to describe solvent transfer in pressure-driven membrane separation processes. The experimental work is carried out in a reverse osmosis (RO) setup by using two different membranes, TFC-HR and TFC-ULP, manufactured by Koch Membranes Systems, Inc. (USA). Characterization for these membranes by using the transmission electron microscopy (TEM) is also presented. Aqueous solutions of sodium chloride and ammonium bicarbonate were used as feed at 15, 25, and 35°C. The results show that water transfer in the feed side of the membrane is controlled by the molecular properties of the solute in addition to the operational conditions. Water permeability in the feed solution has been observed to increase as the solute hydration strength or concentration decrease, and as the temperature and the hydraulic pressure increase. The validated model explains the interaction between water permeability in the feed solution and water permeability inside the membrane material. The model shows good agreement with the experimental results. It provides good description for solvent transfer in membrane separation processes and may be useful for future development and design applications, when based on experimental data.

Original languageEnglish
Pages (from-to)27-33
Number of pages7
JournalJournal of Membrane Science
Volume364
Issue number1-2
DOIs
Publication statusPublished - 15 Nov 2010
Externally publishedYes

Fingerprint

Permeability
permeability
membranes
Membranes
Pressure
Water
water
solutes
Ammonium bicarbonate
Osmosis
reverse osmosis
Sodium Bicarbonate
molecular properties
Reverse osmosis
sodium chlorides
Sodium chloride
Transmission Electron Microscopy
Sodium Chloride
Hydration
hydraulics

Keywords

  • Membrane separation processes
  • Reverse osmosis
  • Solution-diffusion pore-flow fluid-resistance model
  • TEM
  • Water permeability

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Science(all)
  • Biochemistry
  • Filtration and Separation

Cite this

Experimental approaches to feed solution permeability in pressure-driven membrane separation processes. / Toffoletto, M.; Merdaw, A. A.; Sharif, A. O.; Bertucco, A.

In: Journal of Membrane Science, Vol. 364, No. 1-2, 15.11.2010, p. 27-33.

Research output: Contribution to journalArticle

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