Estimating the strength of the M-H-B interaction: A kinetic approach

Muhammad Sohail, Salvador Moncho Escriva, Edward Brothers, Donald J. Darensbourg, Ashfaq A. Bengali

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Photolysis of BzCr(CO)3 and TpMn(CO)3 in the presence of H3B·NEt3 yields a metal-borane σ complex. Displacement of the weakly coordinated borane by P(OEt)3 proceeds by a dissociative mechanism and an Eyring analysis yields the first estimate of 20 kcal mol-1 for the strength of this novel interaction.

Original languageEnglish
Pages (from-to)6720-6723
Number of pages4
JournalDalton Transactions
Volume42
Issue number19
DOIs
Publication statusPublished - 6 May 2013

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Boranes
Carbon Monoxide
Kinetics
Photolysis
Coordination Complexes
Metal complexes

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Estimating the strength of the M-H-B interaction : A kinetic approach. / Sohail, Muhammad; Moncho Escriva, Salvador; Brothers, Edward; Darensbourg, Donald J.; Bengali, Ashfaq A.

In: Dalton Transactions, Vol. 42, No. 19, 06.05.2013, p. 6720-6723.

Research output: Contribution to journalArticle

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