Electrochemical lithium ion intercalation in Li 0.5Ni 0.25TiOPO 4 examined by in situ X-ray diffraction

Rickard Eriksson, Kenza Maher, Ismael Saadoune, Mohammed Mansori, Torbjörn Gustafsson, Kristina Edström

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8 Citations (Scopus)

Abstract

The complex structural transformations of Li 0.5Ni 0.25TiOPO 4 during electrochemical lithiation have been examined by in situ X-ray diffraction. During the first lithiation two structural changes take place: first a transition to a second monoclinic phase (a = 9.085(4), b = 8.414(5), c = 6.886(5), β = 99.85(4)) and secondly a transition to a third phase with limited long-range order. The third phase is held together by a network of corner sharing Ti-O octahedra and phosphate ions with disordered Ni-Li channels. During delithiation the third phase is partially transformed back to a slightly disordered original phase, Li 0.5Ni 0.25TiOPO 4 without formation of the second intermediate phase. These phase transitions correspond well to the different voltage plateaus that this material shows during electrochemical cycling.

Original languageEnglish
Pages (from-to)547-550
Number of pages4
JournalSolid State Ionics
Volume225
DOIs
Publication statusPublished - 4 Oct 2012
Externally publishedYes

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Keywords

  • Batteries
  • In situ X-ray powder diffraction
  • Lithium intercalation compounds

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Chemistry(all)

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