Efficient removal of different basic dyes using graphene

Muhammad Z. Iqbal, Priyabrata Pal, Mohamad Shoaib, Ahmed Abdala

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Adsorptive removal of two basic dyes, methylene blue (MB) and malachite green (MG) using thermally reduced graphene (TRG) is reported. TRG was synthesized by thermal exfoliation and reduction of graphite oxide, and characterized by X-ray diffraction, transmission electron spectroscopy, and surface area measurements. The factors affecting the adsorption process such as initial dye concentration, initial solution pH, temperature, and Dye/TRG ratio were investigated. The Dye/ TRG ratio was found to be the most important factor controlling the adsorption of MB and MG on graphene surface. Highest adsorption capacity was observed at dye/TRG ratio of 1, irrespective of the initial dye concentration. The maximum measured adsorption capacity of 687 mg/g-TRG for MB and 212 mg/g-TRG for MG, and removal efficiency of 99.62% for MB and 98.74% for MG were obtained. Both dyes followed the Langmuir isotherm indicating the monolayer adsorption on the graphene surface. Thermodynamic analysis indicated the adsorption of MB is an exothermic process whereas adsorption of MG is an endothermic process. In addition, an equilibrium model to model the experimental adsorption data was developed which successfully described the experimental adsorption results and predicted maximum theoretical capacity of 730 mg/g-TRG for MB and 380 mg/ g-TRG for MG, consistent with previously reported results for MB adsorption on graphene and its derivatives.

Original languageEnglish
Pages (from-to)226-235
Number of pages10
JournalDesalination and Water Treatment
Volume68
DOIs
Publication statusPublished - 1 Mar 2017

Fingerprint

Graphene
dye
Dyes
malachite
adsorption
Adsorption
removal
Electron spectroscopy
graphite
isotherm
surface area
thermodynamics
spectroscopy
X-ray diffraction
Isotherms
oxide
Monolayers
Graphite
electron
Thermodynamics

Keywords

  • Adsorption
  • Graphene
  • Malachite green
  • Methylene blue
  • Wastewater treatment

ASJC Scopus subject areas

  • Water Science and Technology
  • Ocean Engineering
  • Pollution

Cite this

Efficient removal of different basic dyes using graphene. / Iqbal, Muhammad Z.; Pal, Priyabrata; Shoaib, Mohamad; Abdala, Ahmed.

In: Desalination and Water Treatment, Vol. 68, 01.03.2017, p. 226-235.

Research output: Contribution to journalArticle

Iqbal, Muhammad Z. ; Pal, Priyabrata ; Shoaib, Mohamad ; Abdala, Ahmed. / Efficient removal of different basic dyes using graphene. In: Desalination and Water Treatment. 2017 ; Vol. 68. pp. 226-235.
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