Effect of temperature on the rheological properties of neat aqueous Wyoming sodium bentonite dispersions

Zisis Vryzas, Vassilios C. Kelessidis, Lori Nalbantian, Vassilis Zaspalis, Dimitrios I. Gerogiorgis, Yiming Wubulikasimu

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Temperature affects significantly the rheological behavior of neat water Wyoming Na-bentonite dispersions. The results of a very systematic study are presented regarding rheological measurements of 7% mass concentration at different temperatures, ranging between 25 and 80 °C at atmospheric pressure. Higher temperature increased the shear stresses at low shear rates while the effect was much smaller at higher shear rates. The Herschel-Bulkley rheological model fitted extremely well all data. The yield stress increased linearly with temperature by almost three-fold, the flow consistency index decreased exponentially with temperature by almost five-fold and the flow behavior index increased by about 20%, tending towards the Newtonian value. At low shear rates (< 100 rpm corresponding to < 170 1/s Newtonian shear rates), which represent very well the shear rates experienced by drilling fluids in the critical annulus region, all rheograms appeared fairly linear and the Bingham plastic model fitted well all data. The Bingham yield stress, from the low shear rate data, increased linearly with temperature, while the plastic viscosity decreased with temperature, in a manner very similar to the decrease of water viscosity with temperature. The plastic viscosity and Bingham yield stress data, from the low shear rate range, can be fitted well by an Arrhenius-type equation, with the activation energy for the plastic viscosity very similar to the activation energy for water viscosity, while for the Bingham yield stress, the activation energy is equal but opposite in sign to that of the plastic viscosity. A hypothesis is stated for the the observed linear increase of the yield stress with temperature, in the temperature range studied. One should be concerned when non-standard preparation and measurement procedures are followed which makes extremely difficult to understand any differences observed when reporting rheological data of water bentonite dispersions. A standard methodology is proposed, complementary to API, which can give very consistent results.

Original languageEnglish
Pages (from-to)26-36
Number of pages11
JournalApplied Clay Science
Volume136
DOIs
Publication statusPublished - 1 Feb 2017

Fingerprint

Bentonite
bentonite
Dispersions
Sodium
sodium
Shear deformation
viscosity
Yield stress
Viscosity
plastic
temperature
Plastics
activation energy
Temperature
Water
Activation energy
fold
effect
water
drilling fluid

Keywords

  • Bentonite
  • Drilling fluids
  • High temperature
  • Rheology
  • Sodium montmorillonite
  • Yield stress

ASJC Scopus subject areas

  • Geology
  • Geochemistry and Petrology

Cite this

Effect of temperature on the rheological properties of neat aqueous Wyoming sodium bentonite dispersions. / Vryzas, Zisis; Kelessidis, Vassilios C.; Nalbantian, Lori; Zaspalis, Vassilis; Gerogiorgis, Dimitrios I.; Wubulikasimu, Yiming.

In: Applied Clay Science, Vol. 136, 01.02.2017, p. 26-36.

Research output: Contribution to journalArticle

Vryzas, Zisis ; Kelessidis, Vassilios C. ; Nalbantian, Lori ; Zaspalis, Vassilis ; Gerogiorgis, Dimitrios I. ; Wubulikasimu, Yiming. / Effect of temperature on the rheological properties of neat aqueous Wyoming sodium bentonite dispersions. In: Applied Clay Science. 2017 ; Vol. 136. pp. 26-36.
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AU - Gerogiorgis, Dimitrios I.

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AB - Temperature affects significantly the rheological behavior of neat water Wyoming Na-bentonite dispersions. The results of a very systematic study are presented regarding rheological measurements of 7% mass concentration at different temperatures, ranging between 25 and 80 °C at atmospheric pressure. Higher temperature increased the shear stresses at low shear rates while the effect was much smaller at higher shear rates. The Herschel-Bulkley rheological model fitted extremely well all data. The yield stress increased linearly with temperature by almost three-fold, the flow consistency index decreased exponentially with temperature by almost five-fold and the flow behavior index increased by about 20%, tending towards the Newtonian value. At low shear rates (< 100 rpm corresponding to < 170 1/s Newtonian shear rates), which represent very well the shear rates experienced by drilling fluids in the critical annulus region, all rheograms appeared fairly linear and the Bingham plastic model fitted well all data. The Bingham yield stress, from the low shear rate data, increased linearly with temperature, while the plastic viscosity decreased with temperature, in a manner very similar to the decrease of water viscosity with temperature. The plastic viscosity and Bingham yield stress data, from the low shear rate range, can be fitted well by an Arrhenius-type equation, with the activation energy for the plastic viscosity very similar to the activation energy for water viscosity, while for the Bingham yield stress, the activation energy is equal but opposite in sign to that of the plastic viscosity. A hypothesis is stated for the the observed linear increase of the yield stress with temperature, in the temperature range studied. One should be concerned when non-standard preparation and measurement procedures are followed which makes extremely difficult to understand any differences observed when reporting rheological data of water bentonite dispersions. A standard methodology is proposed, complementary to API, which can give very consistent results.

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