Wpływ warunków redukcji na działanie katalizatora Cs-Cu/ZnO w reakcji syntezy wyższych alkoholi alifatycznych z gazu syntezowego

Translated title of the contribution: Effect of reduction conditions on the performance of the Cs-Cu/ZnO catalyst in the reaction of synthesis of higher aliphatic alcohols from synthesis gas

Lech Nowicki, Tomasz Olewski, Tomasz Bedyk, Stanisław Ledakowicz

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the study, the effect of various activation procedures on subsequent performance of the Cs -Cu/ZnO catalyst in higher aliphatic alcohol synthesis from synthesis gas was investigated in a fixed bed reactor. Additional studies on the degree of catalyst reduction were performed using the termobalance coupled with the mass spectrometer. The best yield was obtained after the reduction with hydrogen followed by the stabilization of the catalyst at high temperature with flowing synthesis gas. The catalyst activated with CO produced more C2+ alcohols than that reduced with hydrogen.

Original languagePolish
Pages (from-to)163-175
Number of pages13
JournalChemical and Process Engineering - Inzynieria Chemiczna i Procesowa
Volume27
Issue number1
Publication statusPublished - 2006
Externally publishedYes

Fingerprint

Synthesis gas
Alcohols
Catalysts
Hydrogen
Mass spectrometers
Carbon Monoxide
Stabilization
Chemical activation
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Wpływ warunków redukcji na działanie katalizatora Cs-Cu/ZnO w reakcji syntezy wyższych alkoholi alifatycznych z gazu syntezowego. / Nowicki, Lech; Olewski, Tomasz; Bedyk, Tomasz; Ledakowicz, Stanisław.

In: Chemical and Process Engineering - Inzynieria Chemiczna i Procesowa, Vol. 27, No. 1, 2006, p. 163-175.

Research output: Contribution to journalArticle

@article{0f149cf7bbb44b7690320ab4ade5d73e,
title = "Wpływ warunk{\'o}w redukcji na działanie katalizatora Cs-Cu/ZnO w reakcji syntezy wyższych alkoholi alifatycznych z gazu syntezowego",
abstract = "In the study, the effect of various activation procedures on subsequent performance of the Cs -Cu/ZnO catalyst in higher aliphatic alcohol synthesis from synthesis gas was investigated in a fixed bed reactor. Additional studies on the degree of catalyst reduction were performed using the termobalance coupled with the mass spectrometer. The best yield was obtained after the reduction with hydrogen followed by the stabilization of the catalyst at high temperature with flowing synthesis gas. The catalyst activated with CO produced more C2+ alcohols than that reduced with hydrogen.",
author = "Lech Nowicki and Tomasz Olewski and Tomasz Bedyk and Stanisław Ledakowicz",
year = "2006",
language = "Polish",
volume = "27",
pages = "163--175",
journal = "Inzynieria Chemiczna i Procesowa",
issn = "0208-6425",
publisher = "Jagellonian University",
number = "1",

}

TY - JOUR

T1 - Wpływ warunków redukcji na działanie katalizatora Cs-Cu/ZnO w reakcji syntezy wyższych alkoholi alifatycznych z gazu syntezowego

AU - Nowicki, Lech

AU - Olewski, Tomasz

AU - Bedyk, Tomasz

AU - Ledakowicz, Stanisław

PY - 2006

Y1 - 2006

N2 - In the study, the effect of various activation procedures on subsequent performance of the Cs -Cu/ZnO catalyst in higher aliphatic alcohol synthesis from synthesis gas was investigated in a fixed bed reactor. Additional studies on the degree of catalyst reduction were performed using the termobalance coupled with the mass spectrometer. The best yield was obtained after the reduction with hydrogen followed by the stabilization of the catalyst at high temperature with flowing synthesis gas. The catalyst activated with CO produced more C2+ alcohols than that reduced with hydrogen.

AB - In the study, the effect of various activation procedures on subsequent performance of the Cs -Cu/ZnO catalyst in higher aliphatic alcohol synthesis from synthesis gas was investigated in a fixed bed reactor. Additional studies on the degree of catalyst reduction were performed using the termobalance coupled with the mass spectrometer. The best yield was obtained after the reduction with hydrogen followed by the stabilization of the catalyst at high temperature with flowing synthesis gas. The catalyst activated with CO produced more C2+ alcohols than that reduced with hydrogen.

UR - http://www.scopus.com/inward/record.url?scp=57649101254&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=57649101254&partnerID=8YFLogxK

M3 - Article

VL - 27

SP - 163

EP - 175

JO - Inzynieria Chemiczna i Procesowa

JF - Inzynieria Chemiczna i Procesowa

SN - 0208-6425

IS - 1

ER -