Effect of CO conversion on the product distribution of a Co/Al 2O3 fischer-tropsch synthesis catalyst using a fixed bed reactor

Dragomir B. Bukur, Zhendong Pan, Wenping Ma, Gary Jacobs, Burtron H. Davis

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

The effect of CO conversion (35-91 %) on hydrocarbon product distribution (CH4, C++ and olefin selectivities) and CO 2 selectivity was studied in a fixed bed reactor on 15 % Co/Al 2O3 catalyst at conditions of industrial relevance. Selectivity to CH4 decreased, whereas those of C5 + and CO2 increased with increasing CO conversion (and consequently, partial pressure of water produced during the Fischer-Tropsch synthesis). 1-Olefin content of C2-C5 olefins decreased and 2-olefin content of C4 hydrocarbon increased with increasing CO conversion.

Original languageEnglish
Pages (from-to)1382-1387
Number of pages6
JournalCatalysis Letters
Volume142
Issue number11
DOIs
Publication statusPublished - 1 Nov 2012

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Keywords

  • Catalyst deactivation
  • Cobalt on alumina catalyst
  • Fischer-Tropsch synthesis
  • Fixed-bed and slurry-bed reactors
  • Product distribution

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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