Dicaesium magnesium bis-(dihydrogen phosphate(V)) dihydrate

Rachid Essehli, Brahim El Bali, Mohammed Lachkar, Michael Bolte

Research output: Contribution to journalArticle

Abstract

The title compound, Cs2Mg(H2P2O7)2·2H2O, is isostructural with the related known isoformular phosphates. The crystal framework consists of corner-sharing MgO6 and H2P2O7 polyhedra, leading to tunnels parallel to the b-axis direction in which Cs+ ions are located. The H2P2O7 unit shows a bent eclipsed conformation. The Mg2+ ion lies on an inversion center. The water molecules form hydrogen bonds to O atoms of two different dihydrogenphosphate ions, which are further hydrogen bonded to symmetry-equivalent dihydrogenphosphate ions.

Original languageEnglish
Pages (from-to)i3
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number1
DOIs
Publication statusPublished - 1 Dec 2008

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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