Development of LiNi0.5 Mn1.5 O4 / Li 4 Ti5 O12 system with long cycle life

H. M. Wu, I. Belharouak, H. Deng, Ali Abouimrane, Y. K. Sun, K. Amine

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

The electrochemical performance of LiNi0.5 Mn1.5 O4 (LNMO) / Li4 Ti5 O12 (LTO) cells with different designs (positive-electrode-limited, negative-electrode-limited, and positive/negative capacity ratio of ≈1) was investigated at different temperatures and current densities. Half-cells based on either LNMO/Li or LTO/Li exhibited an outstanding rate capability. When both electrodes were combined in a full cell configuration, the LNMO/LTO cells showed an excellent rate capability, with 86% discharge capacity retention at the 10C rate. Of the three designs, the negative-limited full cell showed the best cycling performance when discharged at the 2C rate in tests at room temperature: 98% capacity retention after 1000 cycles. The negative-limited full cell also exhibited excellent cycling characteristics in tests at 55°C: 95% discharge capacity retention after 200 cycles. These results clearly demonstrate that the LNMO/LTO system with a negative-limited design is attractive for plug-in hybrid electric vehicles, where a long cycle life and a reasonable power are needed.

Original languageEnglish
JournalJournal of the Electrochemical Society
Volume156
Issue number12
DOIs
Publication statusPublished - 10 Nov 2009
Externally publishedYes

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Life cycle
cycles
Electrodes
Plug-in hybrid vehicles
cells
electrodes
Current density
electric hybrid vehicles
Temperature
plugs
current density
room temperature
configurations
temperature

ASJC Scopus subject areas

  • Electrochemistry
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Renewable Energy, Sustainability and the Environment
  • Condensed Matter Physics

Cite this

Development of LiNi0.5 Mn1.5 O4 / Li 4 Ti5 O12 system with long cycle life. / Wu, H. M.; Belharouak, I.; Deng, H.; Abouimrane, Ali; Sun, Y. K.; Amine, K.

In: Journal of the Electrochemical Society, Vol. 156, No. 12, 10.11.2009.

Research output: Contribution to journalArticle

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