(C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure

Rachid Essehli, Brahim El Bali, Mohammed Lachkar, Michael Dusek, Fejfarova Karla, Michael Bolte

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

(C2N2H10)2Mg(HP 2O7)2·2H2O, is a new inorganic organic hybrid structure. It has been synthetized using wet chemistry. Its crystal structure consists of cis- and trans-edge sharing [MgO 4(H2O)2] octahedra resulting in chains, which are linked via [HP2O7] units to form [Mg(HP 2O7)2(H2O)2] 4- layers. The Mg2+ cations and the ethylendiammonium cations are located on centers of inversion. The ethylendiammonium cations are alternately located in the interlayer space. The cohesion of the crystal is well ensured by coulombic interactions between anions and cations and by several hydrogen bonds. The diphosphate anion shows an eclipsed conformation.

Original languageEnglish
Pages (from-to)655-660
Number of pages6
JournalJournal of Chemical Crystallography
Volume36
Issue number10
DOIs
Publication statusPublished - Oct 2006
Externally publishedYes

Fingerprint

Cations
Crystal structure
cations
crystal structure
synthesis
Anions
anions
diphosphates
hybrid structures
Diphosphates
cohesion
Conformations
Hydrogen
interlayers
Hydrogen bonds
chemistry
inversions
hydrogen bonds
Crystals
crystals

Keywords

  • Diphosphate
  • Layered structure
  • Magnesium

ASJC Scopus subject areas

  • Spectroscopy
  • Condensed Matter Physics
  • Structural Biology

Cite this

(C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure. / Essehli, Rachid; El Bali, Brahim; Lachkar, Mohammed; Dusek, Michael; Karla, Fejfarova; Bolte, Michael.

In: Journal of Chemical Crystallography, Vol. 36, No. 10, 10.2006, p. 655-660.

Research output: Contribution to journalArticle

Essehli, R, El Bali, B, Lachkar, M, Dusek, M, Karla, F & Bolte, M 2006, '(C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure', Journal of Chemical Crystallography, vol. 36, no. 10, pp. 655-660. https://doi.org/10.1007/s10870-006-9113-5
Essehli, Rachid ; El Bali, Brahim ; Lachkar, Mohammed ; Dusek, Michael ; Karla, Fejfarova ; Bolte, Michael. / (C2N2H10)2Mg(HP 2O7)2·2H2O synthesis and crystal structure. In: Journal of Chemical Crystallography. 2006 ; Vol. 36, No. 10. pp. 655-660.
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AU - Karla, Fejfarova

AU - Bolte, Michael

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