Crystal structure and luminescence properties of silver(I) doped polyphosphate NaZn(PO3)3

Hakima Aouad, Mohamed Maazaz, Ilias Belharouak

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the context of a detailed investigation of the luminescent properties of Na1-xAgxZn(PO3)3 (0 < x ≤ 1) compounds, the structure of the orthorhombic form of sodium-zinc phosphate was confirmed and resolved by the Rietveld profilation method. The cell is orthorhombic (S.G. Pbca), with a = 14.259(2), b = 14.234(3), and c = 14.238(4) Å. The structure is characterized by long phosphate chains connected to infinite chains of [NaO6] and [ZnO6] polyhedra sharing faces. When doped with silver ions, two luminescences have been observed. The UV emission is well known as typical of isolated Ag+ ions. The visible emission, interpreted in the most cases in the term of d10-d10 interactions, originates probably from a silver-zinc association.

Original languageEnglish
Pages (from-to)2457-2467
Number of pages11
JournalMaterials Research Bulletin
Volume35
Issue number14-15
DOIs
Publication statusPublished - 1 Nov 2000
Externally publishedYes

Fingerprint

Polyphosphates
Silver
Luminescence
phosphates
Phosphates
Zinc
zinc
Crystal structure
silver
Ions
luminescence
Rietveld method
crystal structure
polyhedrons
ions
Sodium
sodium
cells
interactions
zinc phosphate

Keywords

  • A. Inorganic compounds
  • C. X-ray diffraction
  • D. Crystal structure
  • D. Luminescence

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Crystal structure and luminescence properties of silver(I) doped polyphosphate NaZn(PO3)3 . / Aouad, Hakima; Maazaz, Mohamed; Belharouak, Ilias.

In: Materials Research Bulletin, Vol. 35, No. 14-15, 01.11.2000, p. 2457-2467.

Research output: Contribution to journalArticle

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N2 - In the context of a detailed investigation of the luminescent properties of Na1-xAgxZn(PO3)3 (0 < x ≤ 1) compounds, the structure of the orthorhombic form of sodium-zinc phosphate was confirmed and resolved by the Rietveld profilation method. The cell is orthorhombic (S.G. Pbca), with a = 14.259(2), b = 14.234(3), and c = 14.238(4) Å. The structure is characterized by long phosphate chains connected to infinite chains of [NaO6] and [ZnO6] polyhedra sharing faces. When doped with silver ions, two luminescences have been observed. The UV emission is well known as typical of isolated Ag+ ions. The visible emission, interpreted in the most cases in the term of d10-d10 interactions, originates probably from a silver-zinc association.

AB - In the context of a detailed investigation of the luminescent properties of Na1-xAgxZn(PO3)3 (0 < x ≤ 1) compounds, the structure of the orthorhombic form of sodium-zinc phosphate was confirmed and resolved by the Rietveld profilation method. The cell is orthorhombic (S.G. Pbca), with a = 14.259(2), b = 14.234(3), and c = 14.238(4) Å. The structure is characterized by long phosphate chains connected to infinite chains of [NaO6] and [ZnO6] polyhedra sharing faces. When doped with silver ions, two luminescences have been observed. The UV emission is well known as typical of isolated Ag+ ions. The visible emission, interpreted in the most cases in the term of d10-d10 interactions, originates probably from a silver-zinc association.

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